BACKGROUND Purified terephthalic acid (PTA) wastewater from a petrochemical complex was utilized as a fuel in the anode of a microbial fuel cell (MFC). Effects of two important parameters including different dilutions of the PTA wastewater and pH on the performance of the MFC were investigated. METHODS The MFC used was a membrane-less single chamber consisted of a stainless steel mesh as anod...

A stacking approach based on pH junction and field amplification has been developed for determining amines by capillary electrophoresis (CE) with electrochemiluminescence (ECL) detection. A two-electrode configuration was employed with an indium/tin oxide-coated glass as a working electrode and a platinum wire as a pseudoreference electrode. The ECL system also contains a flow cell (poly(dimeth...

Covalent tethering of P(Ph)2N(C6H4C≡CH)2 ligands (P(Ph)2N(C6H4C≡CH)2 = 1,5-di-(4-ethynylphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) to planar, azide-terminated glassy carbon electrode surfaces has been accomplished using a Cu(I)-catalyzed alkyne-azide cycloaddition (CuAAC) coupling reaction, using a BH3←P protection-deprotection strategy. Deprotected, surface-confined ligands were ...

The accumulation of tetraphenylphosphonium (TPP(+)), 5,5'-dimethyl-oxazolidine-2,4-dione (DMO), and a micro pH electrode were used to measure membrane potential, intracellular and extracellular pH, respectively, upon the addition of exogenous sucrose to soybean cotyledon protoplasts. Addition of sucrose caused a specific and transient (a) depolarization of the membrane potential (measured by TP...

We fabricated a pH-sensitive device on a glass substrate based on properties of carbon nanotubes. Nanotubes were immobilized specifically on chemically modified areas on a substrate followed by deposition of metallic source and drain electrodes on the area. Some nanotubes connected the source and drain electrodes. A top gate electrode was fabricated on an insulating layer of silane coupling age...

Sørensen used a slide-wire potentiometer to make his pH measurements. Here a known potential is applied to counterbalance the potential of the hydrogen cell (i.e. the hydrogen electrode plus the counter electrode) and to reduce its current output to zero, at which point the value of the applied counter-potential is equal to that of the cell potential. Since the point of balance is indicated by...

For use in the calibration of electrometric pH assemblies, 17 standard buffer solutions have been investigated, and pH values at 20°, 25°. and 30° C have been assigned to them. The pH values of these solutions range from 2.27 to 11.68 and are considered accurate to ± 0.02 pH unit. Hydrogensilver-chloride cells without liquid junctions were used for establishing the precise pH values of the buff...