Abstract To simulate the specific material properties of thermoplastic polymers a suitable constitutive model is essential. The parallel rheological framework (PRF) was calibrated and evaluated in this study as potential for polymer stent application. Tensile well recovery tests with different loading rates were performed using PLLA specimens. In order to calibrate model, conducted simulated ac...

Injectable poly-L-lactic acid (PLLA) is world-famous filler used in lipoatrophy and facial rejuvenation because of its collagen neogenesis effect which leads to gradual volume restoration. Until recently, quite a number of unwanted adverse events of PLLA have been reported. However, to the best of our knowledge, paraffinoma as a complication of PLLA has never been reported. We herein describe t...

UNLABELLED Herein, for the first time, we combined poly-l-lactic acid (PLLA) with a strontium borosilicate bioactive glass (BBG-Sr) using electrospinning to fabricate a composite bioactive PLLA membrane loaded with 10% (w/w) of BBG-Sr glass particles (PLLA-BBG-Sr). The composites were characterised by scanning electron microscopy (SEM) and microcomputer tomography (μ-CT), and the results showed...

Stereocomplexation between enantiomeric poly(l-lactide) (PLLA) and poly(d-lactide) (PDLA) provides an avenue to greatly enhance performance of eco-friendly polylactide (PLA). Unfortunately, although the manufacturing of semicrystalline polymers generally involves melt processing, it is still hugely challenging to create high-performance stereocomplexed polylactide (sc-PLA) products from melt-pr...

In this paper, we demonstrate the characteristic spiral cracking that appears on the surface of melt-grown poly(L-lactic acid) (PLLA) spherulites with relatively large sizes (greater than 0.4mm in diameter). The crack occurs via thermal shrinkage upon quenching after crystallization. Although concentric cracks on polymer spherulites have been found to occur in quite a few studies, spiral crack ...

INTRODUCTION Peripheral nerve disruptions, frequently occurring during limb injuries, give rise to serious complications of patients recovery resulting from limitations in neural tissue regeneration capabilities. To overcome this problem bridging techniques utilizing guidance channels gain their importance. Biodegradable polymeric tubes seem to be more prospective then non-degradable materials ...

A complementary approach that combines NMR measurements, analysis of X-ray and neutron powder diffraction data and advanced quantum mechanical calculations was employed to study the α-polymorph of L-polylactide. Such a strategy, which is known as NMR crystallography, to the best of our knowledge, is used here for the first time for the fine refinement of the crystal structure of a synthetic pol...

Particulate reinforcement of polymeric matrices is a powerful technique for tailoring the mechanical and degradation properties bioresorbable implant materials. Dispersion inorganic particles critical to achieving optimal properties, however established techniques such as twin-screw extrusion or solvent casting can have significant drawbacks including excessive thermal particle agglomeration. W...

Atmospheric pressure non equilibrium plasma treatments have been implemented to produce solvent-free Poly-L-lactic acid (PLLA) scaffolds, to improve biocompatibility of PLLA mats and to increase electrolyte uptake of Poly(vinylidene fluoride) (PVDF) separators for lithium batteries. It has been observed that plasma treatments are a suitable way to improve polymeric solution electrospinnability,...