Amphiphilic A2(BC)2 miktoarm star polymers [poly(ϵ-caprolactone)]2-[poly(2-(diethylamino)ethyl methacrylate)-b- poly(poly(ethylene glycol) methyl ether methacrylate)]2 [(PCL)2(PDEA-b-PPEGMA)2] were developed by a combination of ring opening polymerization (ROP) and continuous activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP). The critical micelle conc...

Cycloaddition of nitrile imines 4 generated in situ by the catalytic dehydrogenation of diphenyl hydrazones 3 using Chloramine-T (CAT) as oxidant in glacial acetic acid with enolic form of ethyl acetoacetate 5 afforded Ethyl 3-aryl-5-methyl-1-phenyl-1H-pyrazol-4-carboxylate 6 in 80% yield. The said pyrazoles 6 refluxed with 80% hydrazine hydrate using absolute alcohol as solvent for about 2-3 h...

in this study, the effects of linear and rotational speed of the friction stir welding tool was investigated on the heat generation and distribution at surface and inside of workpiece, material flow and geometry of the welding area of poly methyl methacrylate (pmma) workpiece. the commercial cfd fluent 6.4 software was used to simulation of the process with computational fluid dynamic technique...

various morphologies of silica nanoparticles were synthesized by a microwave-assisted pechini method. silica nanostructures were synthesized via a fast reaction between tetra ethyl ortho silicate and ammonia at presence citric acid and other effective agents in pechini procedure. then for preparation of polymer-matrix nanocomposites, sio2 nanoparticles were added to poly carbonate (pc) and poly...