Quantum chemical calculations reveal that ozone is capable of instigating a series of degradative processes in poly(methyl methacrylate). The crux lies in the self-decomposition of 1,2,4-trioxolane, which undergoes a spin intersystem crossing process and O-O bond cleavage to unravel a triplet biradical intermediate that facilitates auto-degradation of the polymer chain.

A coplanar refractive-diffractive doublet array employing surface-relief diffractive phase elements embedded within poly(methyl methacrylate) microlenses is introduced as an optomechanical building block for optoelectronic integrated systems. The design method, fabrication technology, and results are described. Coplanarity of the quadratic- and linear-phase elements constituting the doublet can...

Magnetite nanoparticles combined with polymers produce white-light emission under multiphoton laser irradiation. Understanding the photonic reaction in magnetite-polymer composites is critical for application of magnetite NPs as photothermal agents. Laser irradiated magnetite nanoparticle-poly(methyl methacrylate) (PMMA) composites exhibit fluorescence due to the carbon double-bond formation re...

Amphiphilic bovine serum albumin-poly(methyl methacrylate) conjugate forms nanoparticles with the uniform size of ~100 nm by self-assembling. Loaded with the hydrophobic anti-tumor drug camptothecin, the nanoparticle efficiently delivers drugs into cancer cells, and thus inhibits ~79% of tumor growth in animals compared with free drug.

Quality Control of Poly(Methyl Methacrylate) to Medical Purpose by Multiple Headspace Extraction Lamia Zuniga Linan,* Anderson Bonon, Nádson M. N. Lima, Rubens Maciel Filho, Flavio Manenti a Instituto de Biofabricação (BIOFABRIS), School of Chemical Engineering. State University of Campinas, UNICAMP, Campinas-SP, Brazil. b Politecnico di Milano, CMIC Dept. “Giulio Natta”, Piazza Leonardo da Vin...

The photodegradation of the azobenzene chromophore DR1 {4-[N-ethyl-N-(2-hydroxyethyl)amino]-4(?)-nitroazobenzene]} incorporated as a side chain or as a guest in a poly(methyl) methacrylate host has been evaluated as a function of wavelength, temperature, and the atmospheric environment. The effects of these variables on the lifetime of DR1-based electro-optic devices is quantified.

A new, simple, two-step method is introduced for preparing hollow particles that are both pH-responsive and redox sensitive. Hollow poly(methyl methacrylate-co-methacrylic acid) particles swell at moderate pH values, form gels in concentrated dispersions and can be disassembled by adding reducing agents.

In this work, we propose and realize new design strategies for flexible solar cells based on the classical GaAs/AlGaAs heterojunction. The InAlP layer was chosen as a sacrificial lift-off process in order to separate heterostructure from substrate, also used poly (methyl methacrylate)membrane substrate. combination of these made it possible achieve relativley high specific power - 778 W/kg.