A new polymer-attached rhodium catalyst on a polyethylene oxide-grafted styrene matrix (TentaGel) is described. The corresponding anchor molecules were prepared by starting from different Boc-protected chiral pyrrolidinebis(ph0sphane)Pd complexes. The crystal structure of [3R,4R)-N-(4-carboxybutanoyl) -3,4 -bis (diphenylphosphany1)pyrrolidine-P, P’] diiodopalladium ( lc ) was determined. The fo...

Far- and mid-infrared multiple photon dissociation spectroscopy has been employed to study both the structure and surface reactivity of isolated cationic rhodium clusters with surface-adsorbed nitrous oxide, Rh(n)N(2)O(+) (n = 4-8). Comparison of experimental spectra recorded using the argon atom tagging method with those calculated using density functional theory (DFT) reveals that the nitrous...

An electrophilic, coordinatively unsaturated rhodium complex supported by borate-linked oxazoline, oxazoline-coordinated silylene, and N-heterocyclic carbene donors [{κ(3)-N,Si,C-PhB(Ox(Me2))(Ox(Me2)SiHPh)Im(Mes)}Rh(H)CO][HB(C6F5)3] (, Ox(Me2) = 4,4-dimethyl-2-oxazoline; Im(Mes) = 1-mesitylimidazole) is synthesized from the neutral rhodium silyl {PhB(Ox(Me2))2Im(Mes)}RhH(SiH2Ph)CO () and B(C6F5...

Deficiencies in mismatch repair (MMR) are associated with carcinogenesis. Rhodium metalloinsertors bind to DNA base mismatches with high specificity and inhibit cellular proliferation preferentially in MMR-deficient cells versus MMR-proficient cells. A family of chrysenequinone diimine complexes of rhodium with varying ancillary ligands that serve as DNA metalloinsertors has been synthesized, a...

The conversion of logistics fuels to hydrogen by steam reforming is attractive but poses great challenge since they contain sulfur up to about 3000 ppm leading to catalyst deactivation due to sulfur poisoning. In this paper, we report the fabrication of nominally doped nanoscale ceriasupported rhodium catalyst matrices for their performance evaluation in sulfur-laden fuel streams. Systematic st...

Deficiencies in the mismatch repair (MMR) pathway are associated with several types of cancers, as well as resistance to commonly used chemotherapeutics. Rhodium metalloinsertors have been found to bind DNA mismatches with high affinity and specificity in vitro, and also exhibit cell-selective cytotoxicity, targeting MMR-deficient cells over MMR-proficient cells. Ten distinct metalloinsertors w...

Since the rst report by Heck et al. on the palladium-catalyzed reaction of carbon monoxide with aryl halides and alcohols or amines, transition metal catalyzed cross-coupling reactions have been developed as a valuable method for creating carbon– carbon bonds. In particular, rhodium-catalyzed carbonylation with a variety of substrates has been studied. These reactions require the addition of C...

Transition metal catalyzed reactions of R-diazo ketones (1) are a powerful means to synthesize complex polycyclic organic frameworks.1 In particular, dirhodium(II) carboxylate and carboxamide catalysts mediate a wide range of synthetic transformations such as cyclopropanation,2 C-H and X-H insertion,3,4 aromatic substitution,5 and ylide formation.6 Enantioselective transformations promoted by c...

introduction rhodium metal is known for its stability in corrosive environments, physical beauty, and its unique properties. rhodium is now widely used for alloying platinum in thermocouples, crucibles, evaporating dishes, weighing boats windings for high-temperature furnaces. it has been applied as a coating material because of the hardness and luster of its surface. rhodium is present at abou...

New square-planar rhodium complexes of the redox-active ligand 9,10-phenenthrenediimine (phdi) have been prepared and studied. The complexes [dpp-nacnac(CH3)]Rh(phdi) (2a; [dpp-nacnac(CH3)](-) = CH[C(Me)(N-(i)Pr(2)C(6)H(3))](2)(-)) and [dpp-nacnac(CF3)]Rh(phdi) (2b; [dpp-nacnac(CF3)](-) = CH[C(CF(3))(N-(i)Pr(2)C(6)H(3))](2)(-)) have been prepared from the corresponding [nacnac]Rh(CO)(2) synthon...