نتایج جستجو برای: selective synthesis
تعداد نتایج: 597246 فیلتر نتایج به سال:
The ability to synthesize arrays of related compounds quickly and with good purity has become critical for a rapid exploration their properties biological or material applications. While number methods have been developed enable this combinatorial synthesis, the existing options were not readily appliable synthesis aurones using simple Knoevenagel condensation approach. In order avoid time, exp...
Selective catalytic synthesis of Z-olefins has been challenging. Here we describe a method to produce 1,2-disubstituted olefins in high Z selectivity via reductive cross-coupling of alkyl halides with terminal arylalkynes. The method employs inexpensive and nontoxic catalyst (iron(II) bromide) and reductant (zinc). The substrate scope encompasses primary, secondary, and tertiary alkyl halides, ...
A successful unified pharmacophore/receptor model which has guided the synthesis of subtype selective compounds is reviewed in light of recent developments both in ligand synthesis and structural studies of the binding site itself. The evaluation of experimental data in combination with a comparative model of the 1 2 2 GABAA receptor leads to an orientation of the pharmacophore model within the...
The first total syntheses of multifidosides A-C have been achieved. The synthetic strategy is characterized by catalytic site-selective acylation of unprotected glycoside precursors in the final stage of the synthesis. High functional-group tolerance of the site-selective acylation, promoted by an organocatalyst, enabled the conventionally difficult molecular transformation in a predictable and...
D-Glucosamine was successfully employed as a chiral auxiliary for the enantioselective synthesis of phosphine oxides. The influence of the anomeric position was also investigated and revealed the excellent ability of the α-anomer to perform this transformation in a highly selective fashion. The methodology employed consisted of three steps: diastereoselective formation of the oxazaphospholidine...
The partial oxidation of methane to synthesis gas was investigated in a novel type of perm selective membrane reactor using Perowskite hollow fibers. The operating behaviour of this membrane reactor integrating the process steps selective separation of oxygen from air, selective O2 transfer in the membrane and oxidation of methane with simultaneous steam reforming was investigated theoretically...
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