A detailed study of the effects of hydrodynamic interaction (HI) and excluded volume (EV), on isolated bead-rod chains in shear flows, where the “rods” are mimicked by stiff Fraenkel springs is presented. It is observed that the deformation behavior at weak and intermediate shear rates is qualitatively similar to that observed for polymer chains in the absence of EV and HI, while that at high-s...

2014 Light scattering was used to study the influence of a shear S on the critical fluctuations (lifetime 03C4) of a binary fluid (cyclohexane-aniline). For the first time we experimentally show that in the region S03C4 > 1 (i) the critical temperature is actually changed 0394Tc(S) ~ S0.53±0.03 and (ii) the susceptibility measured in the flow direction crosses over to a mean-field behavior...

An innovative type called "butterfly-shaped links steel plate shear wall (BLSPSW)" was proposed as a lateral load resisting system. In this novel system, by creating butterfly-shaped links in the four sides of the web plate, the lateral load resisting mechanism is not the development of a diagonal tension field on the web plate (similar to Conventional SPSWs), but the capacity of the system is ...

Gels formed by semiflexible filaments such as most biopolymers exhibit non-linear behavior in their response to shear deformation, e.g., with a pronounced strain stiffening and negative normal stress. These negative normal stresses suggest that networks would collapse axially when subject to shear stress. This coupling of axial and shear deformations can have particularly important consequences...

We report here the nonlinear rheological properties of metallo-supramolecular networks formed by the reversible cross-linking of semi-dilute unentangled solutions of poly(4-vinylpyridine) (PVP) in dimethyl sulfoxide (DMSO). The reversible cross-linkers are bis-Pd(II) or bis-Pt(II) complexes that coordinate to the pyridine functional groups on the PVP. Under steady shear, shear thickening is obs...

This work attempts to explore the dynamic and steady-state rheological properties of chitosan modified clay (CMCs) at highly hydrated state. CMCs with different initial chitosan/clay weight ratios (s) were prepared from pre-exfoliated clay via electrostatic adsorption process. Thermogravimetric analysis and optical microscopy were used to determine the adsorbed content of chitosan (m) in CMCs a...

Gold vicinal surfaces (788), with a high density of steps, along with (111) flat surfaces taken as a reference, have been nanoindented and their resulting penetration curves and related defect structure comparatively analyzed by AFM and atomistic simulations. Stepped surfaces are shown to yield at smaller loads than (111) ones in agreement with calculations of the critical resolved shear stress...

In this study, we characterized and modeled the rheology of TEMPO-oxidized cellulose nanofibril (NFC) aqueous suspensions with electrostatically stabilized and unflocculated nanofibrous structures. These colloidal suspensions of slender and wavy nanofibers exhibited a yield stress and a shear thinning behavior at low and high shear rates, respectively. Both the shear yield stress and the consis...

We generalize the mode-coupling theory of supercooled fluids to systems under stationary shear flow. Our starting point is the generalized fluctuating hydrodynamic equations with a convection term. The method is applied to a two dimensional colloidal suspension. The shear rate dependence of the intermediate scattering function and shear viscosity is analyzed. The results show a drastic reductio...

Coupling shear wall has been highly considered in recent years. Due to architectural limitations, sometimes the architect is forced to use two spans separate from shear wall. The study results have shown that using coupling shear wall will have better results than single wall in structure behavior and the desired performance can be achieved by using thinner plates. Coupling steel shear wall has...