Effect of zirconia nanoparticles (zirconia NPs/ZrO2 NPs) modified by 3 wt.% (glycidyloxypropyl) triethoxysilane – GPTES (m-ZrO2 on some properties epoxy coating such as mechanical properties, thermal stability and anti-corrosion performance was investigated. The obtained results indicated that the addition to could enhance this coating. 2 pure ZrO2 NPs (u-ZrO2 matrix increase (hardness adhesion...

With the aim to enhance interfacial adhesion of a hydrophobic polymer matrix and cellulosic fibers and fillers, chemical surface modifications with silane coupling agents are performed. Thermogravimetric analysis (TGA) could be used to determine the degree of surface functionalization. However, similar thermal properties of treated and untreated cellulose hamper a precise determination of silan...

The authors have studied the effect of plasma power, reactor outgassing rates, and of silane purity on the oxygen, carbon, and nitrogen contents of amorphous silicon material prepared by the very high frequency ~70 MHz! glow discharge technique. The silane purity could be optionally enhanced by the application of a getter-based silane gas purifier. It was found that oxygen incorporation was enh...

This study assessed the effect of different etching time of hydrofluoric acid and ultrasonic cleaning of the etched ceramic surface on the resin microtensile bond strength stability to a feldspathic ceramic. The research hypotheses investigated were: (1) different etching time does not affect the adhesion resistance; (2) ultrasonic cleaning improves the adhesion resistance. Forty-eight (48) blo...

Two grades of metallocene-catalysed LLDPE and one grade of low-density polyethylene (LDPE) have been silane grafted and crosslinked by contact with water and their performance has been compared and evaluated. The effects of vinytrimethoxysilane (VTMOS) levels on the degree of crosslinking for each grade were also studied. It was found that increasing level of silane increases the degree of cros...

A new and efficient method for the facile synthesis of C-2 branched carbohydrates has been developed using an intramolecular radical cyclization fragmentation reaction. The desired C-2 branched glucopyranosides were isolated in 40-84% yield. Additionally, an unexpected furanoside was obtained from a tributyltin iodide-promoted rearrangement of the radical intermediate. The C-2 formyl glycal was...