Determining the Mn valence variation at nanometer scale will be an important advance in study of heterogeneous natural silicates. Here, potential scanning transmission X-ray microscopy L2,3-edges (640–655 eV) as a probe for manganese redox state is evaluated. For this purpose, several Mn-silicates (rhodonite, ardennite, piemontite, Mn4+-silicate, jacobsite) were analysed to identify spectral pa...