نتایج جستجو برای: sio2 supported silyl chromate catalyst

تعداد نتایج: 249311  

A. Javidan M.J. Taghizadeh O. Hosseinchi

A new magnetic nanocatalyst has been prepared using immobilization of vanadate onto aminopropyl functionalized SiO2/Fe3O4(VO3-/NH3+-SiO2/Fe3O4). The obtained magnetic catalyst was characterized by FT-IR, XRD, VSM and SEM techniques and used for sulfoxidation of sulfide compounds to the correspondingsulfoxides in presence of H2O2 as oxidant at room temperature. The optimum of reaction conditions...

2015
Luis Lopez Jorge Velasco Alberto Marinas Saul Cabrera Magali Boutonnet

The thermochemical processing of biomass is an alternative route for the manufacture of fuel-grade ethanol, in which the catalytic conversion of syngas to ethanol is a key step. The search for novel catalyst formulations, active sites and types of support is of current interest. In this work, the catalytic performance of an Rh/MCM-41 catalyst has been evaluated and compared with a typical Rh/Si...

Journal: :Catalysts 2023

Lignin obtained by hydrogenolysis of lignocellulose biomass is a prospective source valuable green fuels and chemicals such as monophenols. One the key factors in chemical decomposition lignin to monophenols an efficient catalyst. Inert porous materials hypercrosslinked polymers are suitable catalytic supports for immobilization noble transition metal nanoparticles. However, do not have acidic ...

Journal: :Catalysts 2023

Stable F-T-based catalyst development in direct CO hydrogenation to higher alcohols is still a challenge at present. In this study, CuFe/SiO2 catalysts with SiO2 support treated piranha solution were prepared and evaluated long-term reaction. The showed total alcohols’ selectivity great stability during reaction of more than 90 h. It was found that the treatment enriched surface hydroxyl groups...

Journal: Polyolefins Journal 2016

Ethylene polymerization was carried out using Phillips chromium catalyst based on silica supports such as silica aerogel, SiO2 (Grace 643), and titanium modified SiO2 (G 643), and the results were compared with other catalysts based on SiO2 (Aldrich), SBA-15(Hex), SBA-15(Sp) and MCM-41. A combination of TGA, DSC, XRD, nitrogen adsorption, SEM, ICP, FTIR and other analyses were used to character...

Journal: :journal of sciences, islamic republic of iran 2014
s. rezayati s. sajjadifar

a mild and green method has been developed for the preparation of coumarins derivatives through the one-pot reactions. in our study,various phenols and ethyl acetoacetate compound in which we used silica-supported boron sulfonic acid [sio2/b(so4h)3] as a new, highly efficient and tri-functional inorganic brønsted acid catalyst were processed under solvent-free condition and thermal. the catalys...

Abdolhamid Bamoniri Bi Bi Fatemeh Mirjalili, Esmat Mohammadnejad

Nano-SbCl5.SiO2 and SbCl5.SiO2 are bench-top catalysts which are reusable, readily available, versatile andefficient for promotion of many acid catalyzed organic reactions. These catalysts do not need specialprecautions for preparation, handling or storage, and they can be stored at an ambient temperature for monthswithout losing their catalytic activity. 4-dihydropyrimidin-2(1H)-ones(thiones) ...

Journal: :Angewandte Chemie 2004
George W Huber Randy D Cortright James A Dumesic

A clean stream of alkanes from renewable biomass resources is obtained through aqueous-phase reforming in a single reactor. Alkanes are produced from biomass-derived sorbitol through a bifunctional pathway (see scheme) that involves the dehydration of sorbitol on acid sites (SiO2/Al2O3) and hydrogenation of intermediates on a metal catalyst under a H2 atmosphere. Hydrogen is produced from sorbi...

Journal: :Faraday discussions 2016
Gareth T Whiting Abhishek Dutta Chowdhury Ramon Oord Pasi Paalanen Bert M Weckhuysen

Zeolite-based catalyst bodies are commonly employed in a range of important industrial processes. Depending on the binder and shaping method chosen, vast differences in the reactivity, selectivity and stability are obtained. Here, three highly complementary micro-spectroscopic techniques were employed to study zeolite ZSM-5-binder interactions in SiO2-, Al2O3-, SiO2 : Al2O3- (2 : 1 mix) and kao...

2017
Xin Wang Jianyue Xue Xinyun Wang Xiaoheng Liu

TiO2-SiO2 composites were synthesized using cetyl trimethyl ammonium bromide (CTAB) as the structure directing template. Self-assembly hexadecyltrimethyl- ammonium bromide TiO2-SiO2/(CTAB) were soaked into silver nitrate (AgNO3) aqueous solution. The Ag-TiO2-SiO2(Ag-TS) composite were prepared via a precipitation of AgBr in soaking process and its decomposition at calcination stage. Structural ...

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