From hexanic extract of aerial parts of Peucedanum ruthenicum M. Bieb (Apiaceae) collected from Mazandaran province of Iran, four triterpenoids namely taraxasterol, y-taraxasterol, poriferasterol and b-sitosterol have been isolated by column chromatography, thin layer chromatography, and crystallization. Their structures were elucidated by spectroscopic methods (UV, IR, MS, 1H and 13C-N...

The aim of the present study is to synthesize the oxovanadium complex of the V3+ ion with isatin sciff bases. Spectroscopic methods have been used to confirm these models of complexation and to understand the structures of the species formed in methanolic solution. We also have isolated a complex of Vanadium (III) with isatin schiff bases in the solid phase.

an anionic fe(ii) complex, (bmim)4[fe(cn)6] (where bmim is 1-butyl-3-methylimidazolium), was synthesized in ionic liquid [bmim][pf6] under reflux condition. the complex was characterized by elemental analysis and spectroscopic methods. the magnetite (fe3o4) nanoparticles were prepared by the hydrothermal and solvothermal (in ionic liquid [bmim][pf6]) methods from (bmim)4[fe(cn)6] as a precursor...

Seven new donor/acceptor oligothiophenes 1-2 were synthesized by Stille coupling in moderate to good yields. Compounds 1-2 were completely characterized by the usual spectroscopic methods. In agreement with the electrochemical and the spectroscopic studies for this compounds the new derivatives prepared, can find application for manufacturing new materials with strong non-linear optical (NLO) p...

In this study, we combined different physico-chemical methods to show the effect of overheating on the quality of golden fry cooking oil. Those methods include spectroscopic methods such us 1H-NMR, 13C-NMR and FTIR. Results showed that both overheating and excessive reuse of golden fry cooking oil seriously affected its quality by increasing its density, viscosity and different indexes like ref...

Solvation is essential for protein activities. To study internal solvation of protein, site-directed mutagenesis is applied. Intrinsic fluorescent probe, tryptophan, is inserted into desired position inside protein molecule for ultrafast spectroscopic study. Here we review this unique method for protein dynamics researches. We introduce the frontiers of protein solvation, site-directed mutagene...

The electronic structures with spin-orbit effects of the zirconium nitride ZrN molecule are investigated by the methods of multireference single and double configuration interaction. The potential energy curves are calculated along with the spectroscopic constants for the lowest-lying 34 spin-orbit states Ω in ZrN. A good agreement is displayed by comparing the calculated spectroscopic constant...