dS and sulfate concentrations were determined in snow pit samples using a thermal ionization mass spectrometric technique capable of 0.2& accuracy and requires !5 lg (0.16 lmol) natural S. The technique utilizes a S–S double spike for instrumental mass fractionation correction, and has been applied to snow pit samples collected from the Inilchek Glacier, Kyrgyzstan and from Summit, Greenland. T...

Ion exchange (IEX) resins can remove natural organic matter (NOM) from drinking water sources. However, the IEX system produces a waste brine rich of sodium, chloride, NOM and sulfate. The treatment aims to recover clean solution sodium that be reused regenerate resin. Previous research showed ceramic nanofiltration partially removes brine, but sulfate removal requires additional treatment. Sul...

Aerosols are harmful to human health and have both direct and indirect effects on climate. China is a major contributor to global emissions of sulfur dioxide (SO2), a sulfate (SO4 2 ) precursor, organic carbon (OC), and black carbon (BC) aerosols. Although increasingly examined, the effect of present and potential future levels of these emissions on global premature mortality and climate change...

Fine powders of brushite CaHPO4·2H2O, ardealite Ca(HPO4)x(SO4)1−x·2H2O (Ca(HPO4)0.5(SO4)0.5·2H2O), and calcium sulfate dihydrate CaSO4·2H2O—all containing sodium chloride NaCl as a reaction by-product—were synthesized from 0.5 M aqueous solution CaCl2, hydrophosphate Na2HPO4 and/or Na2SO4. Powder (Ca(HPO4)0.5(SO4)0.5·2H2O) was by precipitation CaCl2 mixed-anionic simultaneously the hydrogen pho...

ATP sulfurylases from Penicillium chrysogenum, Penicillium duponti, Aspergillus nidulans, and Neurospora crassa are strongly inhibited by 3'-phosphoadenosine-5'-phosphosulfate (PAPS), the product of the second (adenosine-5'-phosphosulfate kinase-catalyzed) reaction in the two-step activation of inorganic sulfate. The v versus [PAPS] plots are sigmoidal. At physiological concentrations of MgATP ...

Pertussis toxin (Ptx) expression and secretion in Bordetella pertussis are regulated by a two-component signal transduction system encoded by the bvg regulatory locus. However, it is not known whether the metabolic pathways and growth state of the bacterium influence synthesis and secretion of Ptx and other virulence factors. We have observed a reduction in the concentration of Ptx per optical ...

Tungsten trioxide (WO3) nanostructures were synthesized by hydrothermal method using sodium tungstate (Na2WO4 2H2O) alone as starting material, and sodium tungstate in presence of ferrous ammonium sulfate [(NH4)2 Fe(SO4)2 6H2O] or cobalt chloride (CoCl2 6H2O) as structure-directing agents. Orthorhombic WO3 having a rectangular slab-like morphology was obtained when Na2WO4 2H2O was used alone. W...

We investigated the effect of surface sulfate formation on the structure and spectroscopic properties of MgO nanocubes using X-ray diffraction, electron microscopy, several spectroscopic techniques, and ab initio calculations. After CS2 adsorption and oxidative treatment at elevated temperatures the MgO particles remain cubic and retain their average size of ∼6 nm. Their low coordinated surface...

Aerosols affect the climate system by changing cloud characteristics. Using the global climate model ECHAM5-HAM, we investigate different aerosol effects on mixed-phase clouds: The glaciation effect, which refers to a more frequent glaciation due to anthropogenic aerosols, versus the de-activation effect, which suggests that ice nuclei become less effective because of an anthropogenic sulfate c...

Alishewanella sp. WH16-1 (= CCTCC M201507) is a facultative anaerobic, motile, Gram-negative, rod-shaped bacterium isolated from soil of a copper and iron mine. This strain efficiently reduces chromate (Cr(6+)) to the much less toxic Cr(3+). In addition, it reduces sulfate (SO4 (2-)) to S(2-). The S(2-) could react with Cd(2+) to generate precipitated CdS. Thus, strain WH16-1 shows a great pote...