Complete mineralization of hazardous organic compounds to innocuous products can be achieved using supercritical water oxidation (SCWO). At typical SCWO process conditions (500 – 650 °C), free radical chemistry has been shown to be the dominant reaction path. Detailed Chemical Kinetic Mechanisms (DCKM), consisting of elementary free-radical reactions, have been used to model the oxidation of a ...

Numerical studies have been carried out to investigate flow instabilities in a natural circulation loop with supercritical CO2. For steady-state and dynamic analyses of the loop under supercritical conditions, a single-channel, one-dimensional model is developed. In this model, equations for the conservation of mass, momentum and energy are discretized using an implicit finite difference scheme...

The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetry was observed at high scan rates. A highly lipophilic room temperature ionic liquid that readily dissolved in supercritical CO(2) with aceto...

To establish the most convenient and effective method to dry tangerine peels, different methods (sun drying, hot-air drying, freeze drying, vacuum drying, and medium- and short-wave infrared drying) were exploited. Our results indicated that medium- and short-wave infrared drying was the best method to preserve nutraceutical components; for example, vitamin C was raised to 6.77 mg/g (D.W.) from...

To explore the collapse of eucalyptus wood cells during the drying process, continuous and intermittent drying were carried out on Eucalyptus urophylla. The shrinkage throughout the intermittent drying process was less than that of continuous drying. According to observations of cells made using scanning electron microscopy (SEM), there was a large difference in the degree of cell collapse betw...

Characteristics of microwave drying of wood strands with different initial moisture contents and geometries were investigated using a commercial 10 small microwave oven under different power inputs. Temperature and moisture changes along with the drying efficiency were examined at different drying scenar­ ios. Extractives were analyzed using gas chromatography=mass spectrometry (GC=MS). The res...

The aim of this study was to enhance the apparent solubility and dissolution properties of flurbiprofen through inclusion complexation with cyclodextrins. Especially, the efficacy of supercritical fluid technology as a preparative technique for the preparation of flurbiprofen-methyl-β-cyclodextrin inclusion complexes was evaluated. The complexes were prepared by supercritical carbon dioxide pro...

In this data article, laboratory experimental investigation results on drying kinetic properties: the drying temperature (T), drying air velocity (V) and dewatering time (Te), each of the factors has five levels, and the experiment was replicated three times and the output: drying rate and drying time obtained, were observed. The experiment was conducted at National Centre for Agricultural Mech...

Supercritical fluid (SCF) technology has become an important tool of materials processing in the lasttwo decades. Supercritical CO2 and H2O are extensively being used in the preparation of a great variety ofnanomaterials. The greatest requirement in the application of nanomaterials is its size and morphology control, which determine the application potential of the nanoparticles, as...

The effects of slice thickness, microwave pre-treatment, and drying temperature on drying orange kumara slices were investigated. The highest drying rate, with minimal loss of colour, occurred at 80°C. Slice thickness did not significantly influence colour but drying time increased with slice thickness. The drying curves fitted the Page thin-layer drying model. Two minutes microwave pre-treatme...