Different regioisomeric and diastereomeric isosorbide mono-epoxides are prepared polymerized to thermally stable relatively rigid biobased linear polyethers.

Nanocomposites were synthesized from reactive thermally stable montmorillonite and aromatic-aliphatic polyamide obtained from 4-aminophenyl sulfone and sebacoyl chloride. Carbonyl chloride terminal chain ends were generated using 1% extra sebacoyl chloride that could interact chemically with the organoclay. The distribution of clay in the nanocomposites was investigated by XRD, SEM, and TEM. Me...

A thermally stable, piezoelectric and pyroelectric polymeric substrate was prepared. This thermally stable, piezoelectric and pyroelectric polymeric substrate may be used to prepare electromechanical transducers, thermomechanical transducers, accelerometers, acoustic sensors, infrared sensors, pressure sensors, vibration sensors, impact sensors, in-situ temperature sensors, in-situ stresshtrain...

We present a transmission electron microscopy ~TEM!/Rutherford backscattering spectrometry ~RBS!/x-ray-diffraction ~XRD! study of Au evaporated on crystalline organic thin films of diindenoperylene ~DIP!. Cross-sectional TEM shows that the preparation conditions of the Au film ~evaporation rate and substrate temperature! strongly determine the interfacial morphology. In situ XRD during annealin...

Nanostructured metals achieve extraordinary strength but suffer from low thermal stability, both a consequence of a high fraction of interfaces. Overcoming this tradeoff relies on making the interfaces themselves thermally stable. Here we show that the atomic structures of bi-metal interfaces in macroscale nanomaterials suitable for engineering structures can be significantly altered via changi...

Light scattering and chemical cross-linking analyses of nucleoside diphosphate kinase (NDK) from moderate halophile, Halomonas sp. 593 (HaNDK), unambiguously demonstrated that this enzyme formed a dimeric structure, in contrast to the Pseudomonas NDK (PaNDK), a nonhalophilic counterpart, and other NDKs from Gram-negative bacteria, which all formed a tetrameric structure. Comparison of HaNDK and...

Most azobenzene-based photoswitches use UV light for photoisomerization. This can limit their application in biological systems, where UV light can trigger unwanted responses, including cellular apoptosis. We have found that substitution of all four ortho positions with methoxy groups in an amidoazobenzene derivative leads to a substantial (~35 nm) red shift of the n-π* band of the trans isomer...

The decay kinetics of the candidate tracers 2naphthalene sulfonate and 2,7-naphthalene disulfonate was studied under laboratory conditions that simulate a hydrothermal environment, with neither compound exhibiting any decay after one week at 330C. These data indicate that these compounds are more thermally stable than any of the previously studied polyaromatic sulfonates. Both of the tracer can...

An efficient semi-implicit second-order-accurate finite-difference method is described for studying incompressible Rayleigh-Bénard convection in a box, with sidewalls that are periodic, thermally insulated, or thermally conducting. Operator-splitting and a projection method reduce the algorithm at each time step to the solution of four Helmholtz equations and one Poisson equation, and these are...