The Mo(13) clusters we previously reported were derived from MoS(2) flakes prepared from bulk MoS(2), although the nature of the precursor species was not fully understood. The existence of the clusters in the condensed phase was a question. Here we report the preparation of MoS(2) nanoflakes from elemental precursors using the sonochemical method and study the gas-phase clusters derived from t...

The pyrrolo[2,1-c][1,4] benzodiazepines (PBDs) are a family of sequence-selective, minor-groove binding DNA-interactive agents that covalently attach to guanine residues. A recent publication in this journal (Raju et al, PloS One, 2012, 7, 4, e35920) reported that two PBD molecules were observed to bind with high affinity to the telomeric quadruplex of Tetrahymena glaucoma based on Electrospray...

the united nations has a multiplex criminal policy to fight against genocide, judicial criminal policy being one of the aspects of this policy. rationally, justice requires that the guilty of genocidal acts be punished, the means of redress be provided for victims of such crimes and finally, the international peace and security be established. un judicial criminal policy regarding genocide is r...

Fe deficiency compromises both human health and plant productivity. Thus, it is important to understand plant Fe acquisition strategies for the development of crop plants which are more Fe-efficient under Fe-limited conditions, such as alkaline soils, and have higher Fe density in their edible tissues. Root secretion of phenolic compounds has long been hypothesized to be a component of the redu...

Objective(s): Silver nanoparticles (Ag NPs) are not only specific physical and chemical properties but also are considered for their antibacterial activity and ecofriendly.Materials and Methods:In this study a simple, cost effective biologically method for Ag+reducing to Ag NPs using Echinops extractas a stabilizer, and reducing agent.Ag NPs were analyzed using UV-Vis spectrometry,TEM, XRD and ...

A symmetrical pyrene derivative chemical structure was prepared by a classical synthetic method such as the Sonogashira cross-coupling reaction. The molecular of product characterised in detail nuclear magnetic resonance (NMR), mass spectrometry (MS) and other methods. Furthermore, optical properties novel products were studied UV-vis photoluminescence spectroscopy. electrochemical molecules fu...