An efficient photo-anode for the dye-sensitized solar cells (DSSCs) should have features of high loading of dye molecules, favorable band alignments and good efficiency in electron transport. Herein, the 3.4 nm-sized SnO2 nanocrystals (NCs) of high crystallinity, synthesized via the hot-bubbling method, were incorporated with the commercial TiO2 (P25) particles to fabricate the photo-anodes. Th...

Different tri-doped TiO2 photocatalysts (Fe-N-P/TiO2, Fe-N-S/TiO2, Fe-Pr-N/TiO2, Pr-N-S/TiO2, and P-N-S/TiO2) were successfully prepared tested in the photocatalytic removal of thiacloprid (THI) under UV-A, visible, direct solar light irradiation. The physical-chemical properties catalysts analyzed by different characterization techniques, revealing that dopants are effectively incorporated int...

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Janne-Petteri Niemelä Name of the doctoral dissertation Thin Films of TiO2 and Related Oxides by ALD/MLD: Tailoring of Transport Properties Publisher School of Chemical Technology Unit Department of Chemistry Series Aalto University publication series DOCTORAL DISSERTATIONS 136/2015 Field of research Inorganic Chemistry Manusc...

Platinum-ion-doped TiO2 (Pt(ion)-TiO2) was synthesized by a sol-gel method, and its visible light photocatalytic activities were successfully demonstrated for the oxidative and reductive degradation of chlorinated organic compounds. Pt(ion)-TiO2 exhibited a yellow-brown color, and its band gap was lower than that of undoped TiO2 by about 0.2 eV. The flat band potential of Pt(ion)-TiO2 was posit...

We performed a density functional theory investigation on the structural and electronic properties of pristine and nitrogen-doped TiO2/Graphene oxide nanocomposites as the adsorbents for the removal of toxic NO molecules in the environment. We presented the most stable adsorption configurations and examined the interaction of NO molecule with these doped and undoped nanocomposites. It turns out...

We studied the electronic and atomic structures of anatase TiO2 codoped with Cr and N using hybrid density functional theory calculations. The nonlocal screened Hartree-Fock exchange energy is partially mixed with the traditional semilocal exchange energy. This not only patches the bandgap underestimation but also improves the description of the anion/cation-driven impurity states and the magne...

Band-gap states in V-doped TiO2 have been studied by photoemission spectroscopy over a range of photon energies encompassing the Ti 3p and V 3p core thresholds. The states show resonant enhancement at photon energies significantly higher than found for Ti 3d states introduced into TiO2 by oxygen deficiency or alkalimetal adsorbates. This demonstrates that the gap states relate to electrons trap...

Water pollution by organic pollutants has been a growing global problem in recent years, for which there is a great demand of efficient technologies for wastewater treatment. Remediation of water by photocatalytic oxidation has several advantages over adsorption or any other conventional techniques. This study reports a easy synthesis technique of a sulfur doped hollow TiO2 nanocatalyst for pho...

The (Nb + In) co-doped TiO2 ceramics were synthesized by conventional solid-state sintering (CSSS) and spark plasma sintering (SPS) methods. The phases and microstructures were studied by X-ray diffraction, Raman spectra, field-emission scanning electron microscopy and transmission electron microscopy, indicating that both samples were in pure rutile phase while showing significant difference i...

Two-step anodization of transparent TiO2 nanotube arrays has been demonstrated with aid of a Nb-doped TiO2 buffer layer deposited between the Ti layer and TCO substrate. Enhanced physical adhesion and electrochemical stability provided by the buffer layer has been found to be important for successful implementation of the two-step anodization process. With the proposed approach, the morphology ...