In this study we have synthesized ZnO nanoparticles of rod-like, sphere-like and flower-like structure in solvothermal route by using different capping agent. With the help of XRD data, using Shearer’s equation the average particle size of different morphologies were calculated as 86, 57 and 26 nm for flower-like, sphere-like and rod-like ZnO respectively. The direct band gap energies of the na...

In this study, perfluorinated phosphonic acid modifications were utilized to modify zinc oxide (ZnO) nanoparticles because they create a more stable surface due to the electronegativity of the perfluoro head group. Specifically, 12-pentafluorophenoxydodecylphosphonic acid, 2,3,4,5,6-pentafluorobenzylphosphonic acid, and (1H,1H,2H,2H-perfluorododecyl)phosphonic acid have been used to form thin f...

H2 production by catalytically ethanol steam reforming (ESR) is an effective and prospective method for the application of fuel cells. However, the catalysts’ desirable activity and stability remains an unprecedented challenge. Herein, a type of Sc2O3-doped Co-ZnO catalyst was developed by a co-precipitation method. The so-constructed Co2Zn1Sc0.3 catalyst exhibited a superb catalytic performanc...

The application of membranes in various industries is one of the most urgent needs to reduce energy consumption and environmental pollutants as well as low investment costs in the process of separation. In this investigation, the optimization of effective parameters for separation of gas mixture of CH4, CO2, O2 and N2 is studied by modified poly(4-met...

Strawberries have a very short post-harvest life mostly due to their relatively high water content, intense metabolic activity and susceptibility to microbial rot. Antimicrobial low-density polyethylene nanocomposite films containing ZnO nanoparticles at different mass fractions were prepared by melt mixing and followed by compression moulding using a hot press machine. Fresh strawberries were ...

Increased production and use of zinc oxide nanoparticles (ZnO-NPs) in consumer products has prompted the scientific community to investigate their potential toxicity, and understand their impact on the environment and organisms. Molecular mechanisms involved in ZnO-NP toxicity are still under debate and focus essentially on high dose expositions. In our study, we chose to evaluate the effect of...

In this study, we report a new multifunctional nanoparticle with antioxidative and antibacterial activities in vitro. ZnO@GA nanoparticles were fabricated by coordinated covalent bonding of the antioxidant gallic acid (GA) on the surface of ZnO nanoparticles. This addition imparts both antioxidant activity and high affinity for the bacterial cell membrane. Antioxidative activities at various co...

The electronic structures of pure and Co-doped ZnO quantum dots (QDs) with sizes up to 300 atoms were investigated using three different density functional theory approximations: local spin density approximation (LSDA), gradient-corrected Perdew–Burke–Ernzerhof (PBE) and the hybrid PBE1 functionals with LANL2DZ pseudo-potential and associated basis set. Qualitative agreement among the three met...

Three-dimensional (3D) nanowire (NW) architectures are considered as superior electrode design for photovoltaic devices compared to NWs or nanoparticle systems in terms of improved large surface area and charge transport properties. In this paper, we report development of lead iodide perovskite solar cells based on a novel 3D TiO2 NW architectures. The 3D TiO2 nanostructure was synthesized via ...

Well-aligned ZnO nanorod arrays (ZNAs) with different sizes in diameter were fabricated on Si substrates by two-step chemical bath deposition method (CBD), i.e. substrate pretreatment with spin coating to form ZnO nanoparticles layer and CBD growth. The effects of substrate pretreatments, pH, angel (θ) between substrate and beaker bottom and growth time (t) on the structure of ZNAs were investi...