نتایج جستجو برای: π conjugated molecules

تعداد نتایج: 248732  

Journal: :Chemistry 2013
Tomohiko Nishiuchi Keita Tanaka Yoshiyuki Kuwatani Jooyoung Sung Tohru Nishinaga Dongho Kim Masahiko Iyoda

All bent out of shape: The solvent of crystallization effectively enhances the emission of flexible, bent, π-conjugated molecules in the crystalline state owing to control of the packing of the molecules in the structure. Multichromism such as thermochromism and vapochromism also arises from the solvent-controlled packing. This crystalline-state emission is attributable to the flexibility of cy...

Journal: :Chemistry 2017
Shota Takamuku Masayoshi Nakano Miklos Kertesz

We show that diradicaloid helical conjugated molecules can display strong through-space bonding interactions. These interactions are analogous to π-stacking pancake bonding widely observed for dimers and other aggregates of stable π-conjugated radicals. We show that these multicenter interactions can have a significant stabilizing effect, but they depend in subtle ways on the specific overlap a...

Journal: :Advanced composites and hybrid materials 2023

The blending of π-conjugated molecules with polymeric semiconductors into a composite system is an effective strategy to promote charge carrier mobility because the transmission path by conductive polymers through electrical bridge connection small organic molecule crystalline domain. In this work, pentacene single crystal was prepared induce conjugated polymer chain alignment semiconductor PDP...

Journal: :The Journal of chemical physics 2013
Troels Markussen

We study coherent phonon transport through organic, π-conjugated molecules. Using first principles calculations and Green's function methods, we find that the phonon transmission function in cross-conjugated molecules, like meta-connected benzene, exhibits destructive quantum interference features very analogous to those observed theoretically and experimentally for electron transport in simila...

2013
Jia Guo Yanhong Xu Shangbin Jin Long Chen Toshihiko Kaji Yoshihito Honsho Matthew A. Addicoat Jangbae Kim Akinori Saeki Hyotcherl Ihee Shu Seki Stephan Irle Masahiro Hiramoto Jia Gao Donglin Jiang

Covalent organic frameworks are a class of crystalline organic porous materials that can utilize π-π-stacking interactions as a driving force for the crystallization of polygonal sheets to form layered frameworks and ordered pores. However, typical examples are chemically unstable and lack intrasheet π-conjugation, thereby significantly limiting their applications. Here we report a chemically s...

Journal: :Nature communications 2014
Shiki Yagai Satoru Okamura Yujiro Nakano Mitsuaki Yamauchi Keiki Kishikawa Takashi Karatsu Akihide Kitamura Akira Ueno Daiki Kuzuhara Hiroko Yamada Tomohiro Seki Hajime Ito

π-Conjugated compounds that exhibit tunable luminescence in the solid state under external mechanical stimuli have potential applications in sensors and imaging devices. However, no rational designs have been proposed that impart these mechano-responsive luminescent properties to π-conjugated compounds. Here we demonstrate a strategy for mechano-responsive luminescent materials by imparting amp...

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