in this report, magnetic iron oxide nanoparticles were synthesized via coprecipitation of fe2+ and fe3+ with ammonium hydroxide, and the surface of synthesized nanoparticles was organically functionalized by commercially available amine coupling agent namely, 3-aminopropyl trimethoxysilane (apts) by using well-known sol–gel method. further reaction of the synthesized fe3o4@apts core-shell magne...

A ternary adduct made up of trinitrobenzene, 2-amino-5-chloropyridine and 9-anthracenecarboxylic acid crystallizes out in two polymorphic forms. The adducts, orange red coloured, are a further example the salt/co-crystal continuum.

The physicochemical similarity of isomers makes their chemical separation through conventional techniques energy intensive. Herein, we report that, instead using traditional encapsulation-driven processes, steric hindrance in metal coordination on the outer surface RhII-based metal–organic polyhedra (Rh-MOPs) can be used to separate pyridine-based regioisomers via liquid–liquid extraction. Thro...

The synthesis of a number carbene PEPPSI-complexes palladium with various pyridine and ligands was carried out by reactions 1,3-bis-(2,6-dibenzhydryl-4-methyl­phenyl)imidazolium chloride IPr*.HCl [compounds 7a-c IPr*PdCl2L’, L’ = (?), 3-chloropyridine (b), 4-dimethylaminopyridine (?)], 1,3-bis-(2,6-diisopropylphenyl)­imida­zo­li­um perchlorate IPr.HClO4 8a,b IPr.PdCl2L’, ?-phenanthroline (b)], ...