A simple and robust solvent suppression technique that enables acquisition of high-quality 1D 1 H nuclear magnetic resonance (NMR) spectra of alcoholic beverages on cryoprobe instruments was developed and applied to acquire NMR spectra of Scotch Whisky. The method uses 3 channels to suppress signals of water and ethanol, including those of 13 C satellites of ethanol. It is executed in automatio...

The concept of two-dimensional (2D) Fourier transformation in NMR was first introduced by Jeener (1) in 1971. Since that time, several hundred different 2D pulse schemes have been proposed in the literature. The selection of experiments that will be described is based on the insight they provide into the basis and generality of 2D NMR, and also on the importance for solving the most common type...

In this paper we discuss further properties of 2D correlation spectroscopy using the global phase angle intensity normalization method. The 2D global phase angle analysis method has been shown to discriminate against arbitrary signal amplitude changes not related to real correlation intensities. We have confirmed that the positive or negative sign of a global phase angle 2D correlation peak is ...

The IR and NMR spectra were coupled with quantum chemical calculations in DFT approach usingthe hybrid B3LYP exchange-correlation functional to confirm the structure of 2-methoxycarbonyl-7-methyl-1,3-thiazino[3,2-b][1,2,4]triazine-4,8-dione 2d.

BACKGROUND The relative length of the second and fourth fingers (2D:4D) may be a sex-linked correlate of prenatal androgen exposure. However, the nature of the sex-linkage is controversial, with evidence for both X- and Y-linkage of the 2D:4D phenotype. AIMS To examine transgenerational effects relating to sex-linkage. In addition, assortative mating on 2D:4D was considered, as well as associ...

BACKGROUND The purpose of this study was to assess the correlation between the 2-dimensional (2D) extent of orbital defects and the 3-dimensional (3D) volume of herniated orbital content in patients with an orbital wall fracture. METHODS This retrospective study was based on the medical records and radiologic data of 60 patients from January 2014 to June 2016 for a unilateral isolated orbital...

The dynamic FTIR spectra of propanol in the argon matrix have been measured using a thermal perturbation by heating sample from T = 11 K to 30 stepping 1 K. 2D Fourier-transform infrared (FTIR) absorption correlation analysis has carried out, main attention being concentrated region O–H stretching vibrations at 3000–3700 cm–1. peaks monomers, two conformers open dimer, and cyclic structures dim...