ru/al2o3 catalysts were prepared by conventional incipient wetness impregnation as well as colloid deposition of rucl3 precursor via in situ reduction with ethylene glycol (polyol) method on alumina support. the samples were characterized by tem, xrd and tpr techniques. the catalytic performance tests were carried out in a fixed-bed micro-reactor under different operating conditions. ethylene g...

Pd nanoparticles (PdNPs) stabilized by methyl cellulose (MC) were synthesized in an aqueous solution, which are monodispersed nanoparticles. PdNPs/α-Al2O3 catalyst was prepared with monodispersed PdNPs and showed better catalytic performance than Pd/α-Al2O3 catalyst prepared by the incipient wetness impregnation method using Pd(NO3)2 as a precursor. The catalysts were characterized by transmiss...

One-dimensional γ-Al2O3 nanofibers were modified with Nb2O5 to be used as an efficient heterogeneous catalyst to catalyze biomass into 5-hydroxymethylfurfural (5-HMF). At low Nb2O5 loading, the niobia species were well dispersed on γ-Al2O3 nanofiber through Nb-O-Al bridge bonds. The interaction between Nb2O5 precursor and γ-Al2O3 nanofiber results in the niobia species with strong Lewis acid si...

Selective reduction of NOx by H2 and CO in excess O2 was studied using a Pd/Al2O3 catalyst. Incipient wetness impregnation into Al2O3 was done using PdCl2 as the metal precursor. The NOx conversion profile was maximal at 423 K (up to 95.2% for 250 ppm CO), at which temperature complete oxidation of H2 and CO occurred. There is a very strong synergic effect when both CO and H2 are simultaneously...

We present an optimized approach for the deposition of Al2O3 (as a model secondary material) coating into high aspect ratio (≈180) anodic TiO2 nanotube layers using the atomic layer deposition (ALD) process. In order to study the influence of the diffusion of the Al2O3 precursors on the resulting coating thickness, ALD processes with different exposure times (i.e., 0.5, 2, 5, and 10 s) of the t...

The composites Au/SiO2, Au/TiO2, Au/Al2O3, ZnO/TiO2, ZnO/Al2O3 and Eu2O3/SiO2, Eu2O3/TiO2 Eu2O3/Al2O3 were prepared using a solid-state method. effect of the polymer precursors was investigated two precursor polymers, Chitosan Poly(styrene-co-4vinylpyridine), (PS-co-4-PVP) in M/MxLy•Chitosan//M’xO’y as well M/MxLy•PS-co-4-PVP//M’xO’y with M’xO’y = SiO2, TiO2 Al2O3. effects on particle size morp...

The structure–property relationship of catalytic supports for the deposition redox-active transition metals is great importance improving efficiency and reusability catalysts. In this work, role alumina support precursors Cu-Fe/Al2O3 catalysts used total oxidation toluene as a model volatile organic air pollutant elucidated. Surface characterization revealed that surface area, pore volume acid ...

A short time (3-10 min) of microwave irradiation on the CuO/ZnO/Al2O3 oxide precursor can result in a unique tailored microstructural modification on the catalyst, leading to a significantly enhanced performance for H2 production from steam reforming of methanol.

The Minnesota Nano Center’s Keller Hall facility includes an atomic layer deposition (ALD) machine that is capable of depositing uniform alumina (Al2O3), hafnium oxide (HfO2), silicon dioxide (SiO2), zinc oxide (ZnO), and titanium dioxide (TiO2). ALD works by building alternate layers on a film using two different precursor gases – one usually supplying the metallic atoms and water vapor (H2O) ...