functionalization of multiwalled carbon nanotubes (mwcnts) with nh2 groups under a one pot reaction is studied. during the first step of the reaction, cl and chcl2 groups were attached to the surfaces of mwcnts through an electrophilic addition reaction. in the second step of process, cl atoms were replaced with nh2 and amino groups (ethylene diamine and butyl amine) under a nucleophilic substi...

Carbon dioxide (CO2) adsorption on unfunctionalized and amino-functionalized SBA-3 materials are investigated and compared in this study. The synthesized materials are characterized by various techniques such as X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) method, Fourier transform infrared (FT-IR) and Scanning electron microscopy (SEM).The isotherms of these materials have been measure...

In this study, we investigated the chemical functionalization of carboxylated multiwalled carbon nanotubes (MWCNT–COOH) by 1-Amino-2-naphthol-4-sulfonic acid (ANSA). The functionalized MWCNTs exhibited good aqueous solubility due to the presence of the –OH and – SO3H groups of ANSA. The antimicrobial activity of the MWCNT–COOH as well as its functionalized multiwall nanotube MWCNT-CO-2-(1-amino...

Amino, bromo, nitro, and naphthalene functionalized UiO-66 metal-organic frameworks have been synthesized through reticular chemistry. UiO-66-NH(2) is shown to be suitable for postsynthetic modification with a variety of anhydrides to generate new, functionalized frameworks.

Carbon nanotubes (CNTs) have been readily functionalized by microwave activation using two different reactions affording functional derivatives characterized by two orthogonally protected amino groups. The doubly functionalized CNTs can serve as multipurpose, versatile synthons in materials science and biological applications.

Gold colloids functionalized with amino acids provide a scaffold for effective DNA binding with subsequent condensation. Particles with lysine and lysine dendron functionality formed particularly compact complexes and provided highly efficient gene delivery without any observed cytotoxicity. Nanoparticles functionalized with first generation lysine dendrons (NP-LysG1) were approximately 28-fold...

[reaction: see text] The synthesis of 2'-deoxycytidine nucleosides bearing amino and thiol groups appended to the 5-position of the nucleobase via a butynyl linker is described. The corresponding triphosphates were then synthesized from the nucleoside and incorporated into oligonucleotides by Vent (exo(-)) DNA polymerase. The ability of Vent (exo(-)) polymerase to amplify oligonucleotides conta...

Treating pathogens is becoming challenging because of multidrug resistance and availability of limited alternative therapies which has further confounded this problem. The situation becomes more alarming when multidrug resistant pathogens form a 3D structure known as biofilm. Biofilms are formed in most of the infections especially in chronic infections where it is difficult to eradicate them b...