ABSTRACT: Roasting is one of the widespread methods for processing of nuts and beans that significantly enhances the flavor, color, texture and appearance of the products. In this research the kinetics and modeling of soybean roasting using combined infrared-hot air system and consumption of energy were investigated. The effect of the hot air temperature (160, 180 and 200 ºC), infrared powers (...

The validity of the Arrhenius equation for dissociative electron attachment rate coefficients is investigated. A general analysis allows us to obtain estimates of the upper temperature bound for the range of validity of the Arrhenius equation in the endothermic case and both lower and upper bounds in the exothermic case with a reaction barrier. The results of the general discussion are illustra...

The effect of chemical reactions on the blast initiation of detonation in gaseous media has been investigated in this paper. Analytical method is based on the numerical solution of onedimensional reactive Euler equations. So far, analyses on the blast initiation of detonation have modeled the combustion process as a one-step chemical reaction, which follows the Arrhenius rate law. Previous stud...

Fission-track annealing models aim to extrapolate laboratory kinetics the geological timescale for application studies. Model trends empirically capture mechanisms of track length reduction. To facilitate interpretation fission-track trends, a formalism, based on quantities already in use study physicochemical processes, is developed and allows calculation rate constants, Arrhenius activation e...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

On short time scales an underlying Arrhenius temperature dependence of the diffusion constant can be extracted from the fragile, super-Arrhenius diffusion of a binary Lennard-Jones mixture. This Arrhenius diffusion is related to the true super-Arrhenius behavior by a factor that depends on the average angle between steps in successive time windows. The correction factor accounts for the fact th...

On decreasing the temperature T , supercooled water and other tetrahedral network-forming liquids, such as BeF2 or SiO2, appear to display a dynamic crossover from non-Arrhenius dynamics (with T -dependent activation energy) to Arrhenius dynamics (with constant activation energy). Simulations for water models show that this crossover occurs on crossing the Widom line TW (P ), the locus of maxim...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...