Abstract During the solidification of binary metal alloys, chemical heterogeneities at product scale over a long distance range (1cm-1m) develop and this has detrimental effect on the resulting mechanical properties of cast products. Macrosegregation is of great concern to alloy manufacturers and end users as this problem persist. In this study, the use of process parameters namely casting spee...

Many random substitutional solid solutions (alloys) will display a tendency to atomically order given the appropriate kinetic and thermodynamic conditions. Such order–disorder transitions will result in major crystallographic reconfigurations, where the atomic basis, symmetry, and periodicity of the alloy change dramatically. Consequently, phonon behavior in these alloys will vary greatly depen...

We consider the initial stage phase separation process in multi-component CahnHilliard systems through spinodal decomposition. Relying on recent work of MaierPaape and Wanner we establish the existence of certain dominating subspaces determining the behavior of most solutions originating near a spatially homogeneous state. It turns out that depending on the initial concentrations of the alloy c...

Glassy alloy rods with diameters up to 1.5mm exhibiting a large supercooled liquid region before crystallization and high mechanical strength were formed in Cu-Zr and Cu-Hf binary alloy systems by the copper mold casting method. The large supercooled liquid region exceeding 40K was obtained in the composition range of 30 to 70 at%Zr and 35 to 60 at%Hf. The largest value of the supercooled liqui...

The objective of the study is to characterise the mechanical properties of Ti-15Zr binary alloy dental implants and to describe their biomechanical behaviour as well as their osseointegration capacity compared with the conventional Ti-6Al-4V (TAV) alloy implants. The mechanical properties of Ti-15Zr binary alloy were characterised using Roxolid© implants (Straumann, Basel, Switzerland) via ultr...

A new kind of biomedical shape memory TiNiAg alloy with antibacterial function was successfully developed in the present study by the introduction of pure Ag precipitates into the TiNi matrix phase. The microstructure, mechanical property, corrosion resistance, ion release behavior in simulated body fluid, cytotoxicity and antibacterial properties were systematically investigated. The typical m...

The density and the specific heat of liquid Au–Cu alloy above and below the melting temperature are investigated in a wide composition range via constant temperature and constant pressure molecular dynamics simulations. The atomic interaction of the alloy is described with the embedded-atom method (EAM). The equilibrium melting temperature is evaluated from the change in the growth direction of...

Cobalt-nickel (Co-Ni) binary alloy nanowires of different compositions were co-deposited in the nanopores of highly ordered anodic aluminum oxide (AAO) templates from a single sulfate bath using alternating current (AC) electrodeposition. AC electrodeposition was accomplished without modifying or removing the barrier layer. Field emission scanning electron microscope was used to study the morph...

The effect of binary alloy disorder on the ferromagnetic phases of f-electron materials is studied within the periodic Anderson model. We find that disorder in the conduction band can drastically enhance the Curie temperature T{c} due to an increase of the local f moment. The effect may be explained qualitatively and even quantitatively by a simple theoretical ansatz. The emergence of an alloy ...