Combustion kinetics ...................................................................................................................................... 1 Physical mixing and its effects on ignition, propagation and extinction ...................................................... 2 Mixing ...........................................................................................................

Alumina-supported manganese catalysts with cryptomelane and/or birnessite structure have been prepared using a simple method based on the thermal decomposition of potassium permanganate. The samples have been characterized by XRD, FTIR, TGA, DSC, N2 adsorption at −196 °C, SEM, H2-TPR and XPS, and their catalytic activity for soot combustion has been tested and compared to that of a reference Pt...

in this paper, labo3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. lacoo3 perovskite formulation showed the highest activity among labo3 (fe, mn and co) perovskite catalysts. so, lacoo3 perovskite based catalyst was s...

A new technique is presented for continuous measurements of hydrogen contamination by air in the upper explosive limit range. It is based on the application of a catalytic combustion sensor placed in a cell through which the tested sample passes. The air content is the function of the quantity of formed heat during catalytic combustion of hydrogen inside the sensor. There is the possibility of ...

Combustion catalysts have been extensively explored to reduce the emission of hydrocarbons that are capable of triggering photochemical smog and greenhouse effect. Palladium as the most active material is widely applied in exhaust catalytic converter and combustion units, but its high capital cost stimulates the tremendous research on non-noble metal candidates. Here we fabricate highly defecti...

203 Marco J. Castaldi is an Assistant Professor in the Earth & Environmental Engineering Department at Columbia University. He received his B.S. ChE from Manhattan College and M.S. and Ph.D. ChE from the University of California, Los Angeles. Prior to joining Columbia University, he worked in industry for 7 years researching and developing novel catalytic reactors. His teaching interests lie in...

Computational fluid dynamic (CFD) modeling of full-scale catalytic converters with realistic chemistry has remained elusive primarily due to the extreme computational requirements. In this work, a new low-memory coupled implicit solver, based on the conservative unstructured finite-volume method, was utilized to simulate laboratory-scale catalytic converters with implicit coupling between fluid...