hydroponic experiments were performed to exam the dynamic change of endogenous proline in rice seedlings exposed to potassium chromate chromium (vi) or chromium nitrate chromium (iii). although accumulation of both chromium species in rice seedlings was obvious, more chromium was detected in plant tissues of rice seedlings exposed to chromium (iii) than those in chromium (vi), majority being in...

It has been proposed that 90% of American's diets are deficient in the trace essential mineral chromium. Several chromium(III) dietary supplements are currently available to alleviate this deficiency. We show here that the same pharmacokinetic models that have been used to quantitate absorption of chromium(III) in humans predict that ingested chromium(III) will accumulate and be retained in hum...

a simple ion imprinted amino-functionalized sorbent was synthesized by coupling activated carbon with iminodiacetic acid, a functional compound for metal chelating, through cyanoric chloride spacer. the resulting sorbent has been characterized using fourier transform infrared spectroscopy (ft-ir), elemental analysis, thermogravimetric analysis (tga) and evaluated for the preconcentration and de...

The extraction of chromium(III) from a model waste solution and also from a waste solution of an Indian tannery with Amberlite IR 120 resin is described, and the performance of this resin is compared with other similar resins. The parameters that were optimized include effect of mixing time, pH, loading and elution behaviours of chromium(III) for this resin. Sorption of chromium(III) on Amberli...

the use of an inorganic phase in water-in-oil (w/o) microemulsion has recently received considerable attention for preparing metal oxide nanoparticles. this is a technique, which allows preparation of ultrafine metal oxide nanoparticles within the size range 40 to 80 nm. preparation of nano chromium (iii) oxide studied investigated in the inverse microemulsion system. therefore the nucleation o...

The chromium (III) metformin hydrochloride complex as a diabetic drug model was synthesised by the chemical reaction between chromium (III) chloride hexahydrateand metforminHCl (Mfn.HCl) in methanol solvent. The [Cr(Mfn-HCl)2(Cl)2].Cl.6H2O complex was characterized using microanalytical measurements, molar conductance, spectroscopic (infrared, and UV-vis.), effective magnetic moment, and therma...

A new simple arid rapid catalytic kinetic method for determination of trace amounts of chromium (110 isdescribed. The method is based on the catalytic effect of chromium (III) on the reduction of Methylene blue byascorbic acid in acidic media. The reaction monitored smectrophotomenically by measuring the decrease ofabsorbance at 664 nm at 25 C. The fixed-time method was used for the first 300 s...

Four chromium based oxo-trinuclear carboxylate complexes were prepared by reacting chromium(III) nitrate nonahydrate with acetic acid and substituted carboxylic acids. They were characterized using infrared spectroscopy (FT-IR). Chromium content of the complexes was determined by titrimetry method. The chromium(III) monochloroacetate complex, [Cr3O(ClCH2COO)6.3H2O]NO3.3H2O in combination with d...

a new kinetic spectrophotometic method for the determination of trace amount chromium (iii) in teareal samples has been described based on it s the catalytic effect on the oxidations of 1 - ( 2 –pyridylazo ) - 2 - naphthol, (pan), by potassium bromated in sulfuric acid. the reaction is followedspec- trophotometrically by measuring the decrease in the absorbance at 469 nm. under the optimumcondi...

chromium(III) up to 100 ng mL−1, and for chromium(VI) up to 200 ng mL−1) were obtained, using the “fixed time” method with detection limits of 4.9 ng mL−1 and 3.8 ng mL−1, respectively. The results suggest that at the reaction conditions chromium(VI) is reduced and chromium(III) is oxidized to an intermediate oxidation state and the catalytic action of chromium is due to the formation of an act...