In this work, we developed a circular dichroism (CD) imaging microscope with a device to suppress the commingling of linear birefringence (LB) and linear dichroism (LD) signals. CD signals are, in principle, free from the commingling influence of LD and LB if the sample is illuminated with pure circularly polarized light, with no linear polarization contribution. Based on this idea, we here pro...

Non-chiral metal nanoparticles conjugated with chiral oligonucleotide molecules demonstrated a circular dichroism (CD) at the plasmonic wavelengths due to aggregation effects.

Here we report on a nanoscale circular dichroism (CD) imaging for a two-dimensional chiral pair of nanostructures to elucidate the relationship between nanoscale chirality and CD activity. The chiral pair exhibited local ellipticity as high as 42 degrees in the CD signal at the center, with signals of both handedness coexisting in one nanostructure.

The DICHROWEB web server enables on-line analyses of circular dichroism (CD) spectroscopic data, providing calculated secondary structure content and graphical analyses comparing calculated structures and experimental data. The server is located at http://www.cryst.bbk.ac.uk/cdweb and may be accessed via a password-limited user ID, available upon completion of a registration form. The server fa...

Introduction Circular dichroism (CD) is the most widely used form of chiroptical spectroscopy, spectroscopic techniques that utilize the differential interaction of molecules with left− and right−circularly polarized light. In the absence of a magnetic field, the molecule must be chiral to give rise to a difference in the interaction with the two types of circularly polarized light. The phenome...

Synopsis A calculation has been done of the circular dichroism (CD) spectrum of an unordered polypeptide chain. This has been based on a Boltzmann averaging over a dipeptide conformational CD map. This is shown to be valid by comparing the CD spectra of 28-mer oligopeptides with those generated by summing dipeptide CD spectra. The calculated CD spectrum of an unordered polypeptide chain is foun...

Novel copper(II) coordination compounds with chiral macrocyclic imine ligands derived from R-/S-camphor were asymmetrically synthesized and characterized with the aid of chiroptical spectroscopies. Crystal structures of both enantiomers were determined by single crystal X-ray diffraction analysis. Circular dichroism (CD) spectra were analyzed using a simplified exciton model as well as quantum ...

We have found that racemic mixtures of chiral single-walled nanotubes (SWNTs) wrapped with d(GT)20 DNA oligomer exhibit circular dichroism (CD). We attribute the CD signal to induced CD arising from the coupling of transition moments of the SWNTs and the DNA. Although the nanotube mixture appears to contain both enantiomers in equal amounts, DNA-SWNT transition moment interaction is more constr...

A substituted 3H-indole-modified -cyclodextrin ( -CD), mono-6-deoxy-(2-[(p-amino) phenyl]-3,3-dimethyl-5-carboxyl-3H-indole)-CD (compound A) has been synthesized and characterized by elemental analysis, mass spectrum (MS) and 1H NMR. Induced circular dichroism ( c c C g ©