Activity of cobalt and iron catalysts in ammonia synthesis was determined under a pressure of 10 MPa and at the temperature range of 673–823 K, in a sixchannel integral steel reactor. The catalytic ammonia decomposition was studied in a differential reactor under the atmosphere of low concentration of ammonia (\6%) in the temperature range of 673–823 K under atmospheric pressure. The determined...

the potential of carbon nanotubes (cnt) supported cobalt catalysts for fischer-tropsch (ft) reaction is shown. using the wet impregnation method cobalt on carbon nanotubes catalysts were prepared with cobalt loading varying from 15 to 45 wt. %. the catalysts are characterized by different methods including: bet physisorption, x-ray diffraction, hydrogen chemisorption, and temperature-programmed...

Multiwalled carbon nanotubes (MWCNTs) were functionalized with salicylic acid (SA). The copper-cobalt catalyst was impregnated on the SA functionalized MWCNTs (SA-MWCNTs). The catalyst copper-cobalt/SA-MWCNTs was used to catalyze the synthesis of alcohols from synthesis gas. Salicylic acid can promote the synthesis of ethanol and butanol from synthesis gas, thus reducing the synthesis of methan...

The silylation of SBA-15 enhances the reducibility of cobalt oxides on a SBA-15 supported cobalt catalyst, and consequently increases the catalytic activity for Fischer-Tropsch synthesis of hydrocarbons from syngas and selectivity for longer chain products.

the effects of electronic properties of inner and outer surfaces of carbon nano tubes (cnts) on the deactivation of cobalt fischer-tropsch (ft) catalysts were studied. the comparative characterization of the fresh and used catalysts by tem, xrd, tpr, bet and h2 chemisorption showed that cobalt re-oxidation, cobalt-support interactions and sintering are the main sources of catalyst deactivation....

A weak surface modification is applied to Co/SiO2 catalyst by hydrothermal treatment at 180°C for 5 h. Aluminum is introduced to Co/SiO2 catalysts during the surface modification. The effects of surface modification on Co/SiO2 catalyst are studied by changing the operating sequences of surface modification and cobalt impregnation in the catalyst preparation. Surface modification before cobalt i...

Hybrid photocatalysts were prepared by depositing a macrocyclic cobalt complex on TiO2 surfaces. Upon UV light irradiation, photoexcited electrons in TiO2 nanoparticles were transferred to the surface cobalt catalyst for CO2 reduction.

The structure-activity relations in the alumina-supported cobalt catalysts are studied at the realistic conditions of Fischer-Tropsch synthesis using in situ time-resolved XRD and catalytic measurements. Cobalt sintering during the first 3-5 h of the reaction and cobalt carbidisation at a longer time on stream (>8 h) coincide with catalyst deactivation.

A series of cationic cobalt porphyrins was found to catalyze electrochemical water oxidation to O2 efficiently at room temperature in neutral aqueous solution. Co-5,10,15,20-tetrakis-(1,3-dimethylimidazolium-2-yl)porphyrin, with a highly electron-deficient meso-dimethylimidazolium porphyrin, was the most effective catalyst. The O2 formation rate was 170 nmol · cm(-2) · min(-1) (k(obs) = 1.4 × 1...

Replacement of precious platinum with efficient and low-cost catalysts for electrocatalytic hydrogen evolution at low overpotentials holds tremendous promise for clean energy devices. Here we report a novel type of robust cobalt-nitrogen/carbon catalyst for the hydrogen evolution reaction (HER) that is prepared by the pyrolysis of cobalt-N4 macrocycles or cobalt/o-phenylenediamine composites an...