نتایج جستجو برای: complex cobalt ii

تعداد نتایج: 1332367  

Journal: :Dalton transactions 2016
Jong Won Shin Ah Rim Jeong Sun Young Lee Cheal Kim Shinya Hayami Kil Sik Min

The coordination chemistries of the tetradentate N2O2-type ligands N-(2-pyridylmethyl)iminodiethanol (H2pmide) and N-(2-pyridylmethyl)iminodiisopropanol (H2pmidip) have been investigated with nickel(ii) and cobalt(ii/iii) ions. Three novel complexes prepared and characterized are [(Hpmide)2Ni3(CH3COO)4] (1), [(Hpmide)2Co3(CH3COO)4] (2), and [(pmidip)2Co3(CH3COO)4] (3). In 1 and 2, two terminal ...

Journal: :Dalton transactions 2011
Mihaela Cibian Sofia Derossi Garry S Hanan

Novel hydroxyamidinate complexes of cobalt(II) are presented, together with their electrochemical and spectroscopic properties. An unusual d(7) square-planar coordination around the cobalt(II) center exists and was confirmed by chemical oxidation to its Co(III) species. The Co(II) complex is difficult to reduce, but its facile oxidation suggests that it may be useful as an electron donor in pho...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه شیراز - دانشکده علوم 1390

this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...

Journal: :Australian Journal of Chemistry 1976

Journal: :journal of the iranian chemical research 0
natarajan raman research department of chemistry, vhnsn college, virudhunagar-626 001, india ramaraj jeyamurugan research department of chemistry, vhnsn college, virudhunagar-626 001, india jeyasekaran joseph department of pharmaceutical chemistry, manonmanium sundaranar university, tirunelveli-627 012, india

a new series of transition metal complexes of co(ii), ni(ii), cu(ii) and zn(ii), has beensynthesized from the knoevenagel condensate schiff base ligand(l) derived from β-ketoanilideand furfural with o-phenylenediamine and diethylmalonate. structural features were determinedby spectral and analytical techniques. square-planar geometry has been adopted by thecomplexes except cobalt complex which ...

2013
Xu-Jian Luo Xiu-Qing Zhang

The title complex, [CoNa(CO5P)(H2O)5]n, was obtained by reacting sodium phosphono-formate with cobalt nitrate. The complex contains cobalt(II) and sodium ions, which are bridged by the O atoms of two aqua ligands. The Co(II) ion is octahedrally coordinated by three phosphonoformato ligands (one bi- and the other monodentate) and by two O atoms from the bridging aqua ligands. The sodium cation i...

2010
Brij B. Tewari

A recent technique involving the use of paper electrophoresis is described for the study of equilibria in binary complex systems in solution. The stability constants of the ML and ML2 complex species of some metal ions, namely beryllium(II) and cobalt(II), with hydroxyproline were determined in 0.1 mol L perchloric acid and a temperature of 35 °C. The logarithm stability constants of the ML and...

2017
Ramadan Mohamed Elmehdawi Mohamed Nasir EL-Kaheli Ramadan Gamodi Abuhmaiera Fathia Ali Treish Mufida El Mabruk Ben Younes Carla Bazzicalupi Annalisa Guerri Andrea Caneschi Asma Amjad

The mixed Co(II)/Ni(II) complex, [Co2.67Ni1.33L₄(CH₃COO)₂][BPh₄]₂·0.75H₂O where HL = 4-(salicylaldimine)antipyrine, was isolated as an orange solid from the reaction of 4-(salicylaldimine)antipyrine, with mixed cobalt(II) acetate and nickel(II) acetate in ethanol. The complex was characterized by Frustrated Total Internal Reflection (FTIR), UltraViolet Visible spectroscopy (UV-Vis), X-ray singl...

2014
Ramya R. Rao Catherine L. Lawson

The crystal structure of cyclic AMP-catabolite activator protein (CAP) from Escherichia coli containing cobalt(II) chloride and ammonium sulfate is reported at 1.97 Å resolution. Each of the two CAP subunits in the asymmetric unit binds one cobalt(II) ion, in each case coordinated by N-terminal domain residues His19, His21 and Glu96 plus an additional acidic residue contributed via a crystal co...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه تبریز - دانشکده علوم طبیعی 1391

in recent years many researchers have been focused on interaction of small molecules with dna. dna is generally the primary intracellular of anticancer drugs, so the interaction between small molecules and dna can cause dna damage in cancer cells, blocking the division of cancer cells and resulting in cell death. the flavonoids are a large group of polyphenolic natural products that are widely ...

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