Here we explored the possibility of using CuInS2-based nanocrystals as colour converting materials for light-emitting applications. Using a mixture of red and green emissive CuInS2-based nanocrystals, we successfully fabricated high colour rendering white light-emitting diodes with surface mounted devices and high-power types. The devices exhibit improved luminous efficiency, high colour render...

Nearly monodisperse alloyed (CuInS2)x(ZnS)1-x nanocrystals with cubic and hexagonal phases were successfully synthesized for the first time, and the band gaps of these alloyed nanocrystals can be tuned in the broad range of 1.5 to 3.7 eV by changing the ratio of CuInS2 to ZnS.

Luminescent solar concentrator (LSC) incorporated with quantum dots (QDs) have been widely regarded as one of the most important development trends of cost-effective solar energy. In this study, for the first time we report a new QDs-LSC integrated with heavy metal free CuInS2/ZnS core/shell QDs with large Stokes shift and high optical efficiency. The as-prepared CuInS2/ZnS QDs possess advantag...

Well-aligned ZnO nanorods were uniformly coated with a layer of CuInS2 nanoparticle photosensitizers using a tailored sequential pulsed electrodeposition. The formation of CuInS2-ZnO heterojunction with well-matched band energy alignment and the superior electron mobility in ZnO nanorods led to a remarkable 3.75 times improved photoelectrochemical performance of the electrode under visible ligh...

The capacity of fluorescent colloidal semiconductor nanocrystals for commercial application has led to the development of nanocrystals with nontoxic constituent elements as replacements for the currently available Cd- and Pb-containing systems. CuInS2 is a good candidate material because of its direct band gap in the near-infrared spectral region and large optical absorption coefficient. The te...

In this paper, we developed a near-infrared mercaptopropionic acid (MPA)-capped CuInS2 quantum dot (QD) fluorescence probe for the detection of acid phosphatases (ACP), which is an important biomarker and indicator of prostate cancer. The fluorescence of CuInS2 QDs could be quenched by Cu(2+), and then the addition of adenosine-5'-triphosphate (ATP) could effectively turn on the quenched fluore...

Heterojunction solar cells based on colloidal nanocrystals (NCs) have shown remarkable improvements in performance in the last decade, but this progress is limited to merely two materials, PbS and PbSe. However, solar cells based on other material systems such as copper-based compounds show lower power conversion efficiencies and much less effort has been made to develop a better understanding ...

CuInSe2 and CuInS2 form a continuous solid solution in which the optical bandgap varies from 1.0 to 1.55 eV [1]. By reacting CuInSe2 films in a flowing H2S/Ar atmosphere, the films can be completely converted to CuInS2 or converted to a graded CuIn(Se1-ySy)2 film, depending on processing conditions. A phenomenological model of the reaction/diffusion process is presented wherein H2S reacts with ...

In this paper, to improve the power conversion efficiencies (PCEs) of quantum dot-sensitized solar cells (QDSSCs) based on CdS-sensitized TiO2 nanotube (TNT) electrodes, two methods are employed on the basis of our previous work. First, by replacing the traditional single-sided working electrodes, double-sided transparent TNT/ITO (DTTO) electrodes are prepared to increase the loading amount of ...

Quantum dot sensitized solar cells (QDSCs) constitute one of the most promising low-cost solutions that currently are explored for the world’s needs of clean and renewable energy. Efficient, low-toxic and stable QDSCs for large-scale applications have therefore formed the subject for much of the solar cell research during recent years. This circumstance also forms the basic motivation f...