Highly siliceous ZSM-5 nanocatalysts can dehydrate methanol to a wide range of hydrocarbons. In this study, the development of hierarchical H-ZSM-5 nanocatalysts (Si/Al=200) were reported for the methanol-toolefins (MTO) reaction. The nanocatalysts were prepared through a hydrothermal technique and treated by NaOH desilication. The parent and desilicated nanocatalysts were characterized using F...

Developing highly selective and efficient bifunctional catalysts is an important issue for the hydroisomerization of long-chain n-alkanes. It vital to tailor balance isomerization cracking reactions in hydroisomerization. Herein, a Pt/hierarchical SSZ-32 catalyst was fabricated with sequential desilication–dealumination treatment boost n-hexadecane (C16). The pore structure acid sites zeolite w...

low grade diasporic bauxite in the jajarm mine with an a/s (al2o3/sio2) ratio of 2.3 is not usable in the bayer process at jajarm alumina complex. due to the severe interlocking effect between the diaspore and aluminosilicate minerals (chamosite and kaolinite) and iron-containing minerals in a microcrystal matrix, the thermo-chemical treatment, which is independent from micro-mineralogy, was ch...

High-alumina coal fly ash (HAFA: 45% Al2O3 and 40% SiO2) is regarded as a special solid waste that generated from power plants in northwestern China. It an important substitute for bauxite applied to prepare mullite-based ceramics. In this work, hydrometallurgy–pyrometallurgy synergistic process proposed resolve the lower Al2O3/SiO2 mass ratio (Al/Si) degree of crystallinity can promote formati...

Tectonic inclusions within the New Idria serpentine body contain jadeite in two distinct assemblages: (1) Lenslike inclusions containing a monomineralic green jadeite core surrounded by a calc-silicate rim. (2) Jadeite veins cross-cutting albite-crossite schist inclusions. In these veins jadeite coexists with low albite; green jadeite (Jd 75 Ac+Di+He 25) coexists with low albite within the host...

The synthesis of ZSM-22 zeolite has been extensively studied due to its properties form selectivity, acidity and hydrothermal stability, which is applied in important reactions the areas petroleum refining petrochemicals. In view this, present work different approaches using: 1-diaminohexane as a structure directing agent, (ii) methanol seed crystals, (iii) aging gel with addition polymer, surf...