Thin-film electrodes for a low-power direct methanol fuel cell DMFC were prepared by incorporating carbon-supported Pt nanoparticles Pt/C into a silicon dioxide glass matrix. The SiO2 matrix was prepared via a sol-gel technique where tetraethyl orthosilicate TEOS was hydrolyzed by H2O in the presence of methanol. The Pt/C was stirred into the sol and the resulting mixture was applied to a glass...

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Petri Kanninen Name of the doctoral dissertation Characterization of nanostructured catalysts and silicon microstructures in polymer electrolyte membrane fuel cells Publisher School of Chemical Technology Unit Department of Chemistry Series Aalto University publication series DOCTORAL DISSERTATIONS 76/2014 Field of research Ph...

This work reports the voltammetric behaviour of decamethylcobaltocenium, DmCc(+), in different ionic liquids for the first time. Its redox potential was studied relative to that of decamethylferrocene, DmFc, and it is shown that the difference in the mid-point potential between these two permethylated transition-metal sandwich complexes is independent of the ionic liquid composition. A variable...

Sulfonic acid-functionalized polymer electrolyte membranes alternative to Nafion(®) were developed. These were hydrocarbon systems, such as blend sulfonated polyetheretherketone (s-PEEK), new generation perfluorosulfonic acid (PFSA) systems, and composite zirconium phosphate-PFSA polymers. The membranes varied in terms of composition, equivalent weight, thickness, and filler and were investigat...

Polymer electrolyte membranes (PEM) and Pt-based catalysts are two crucial components which determine the properties and price of fuel cells. Even though, PEM faces problem of fuel crossover in liquid fuel cells such as direct methanol fuel cell (DMFC) and direct borohydride fuel cell (DBFC), which lowers power output greatly. Here, we report a DBFC in which a polymer fiber membrane (PFM) was u...

0014-3057/$ see front matter 2010 Published b doi:10.1016/j.eurpolymj.2010.03.005 * Corresponding author. Tel.: +82 2 958 5299; fax E-mail address: [email protected] (H.-J. Kim). Polymer blending is used to modify or improve the dimensional and thermal stability of any two different polymers or copolymers. In this study, both sulfonated polybenzimidazole homopolymer (MS-p-PBI 100) and sulfonat...

Herein, graphene oxide nanosheets (GO) were synthesized and employed as an additive at various proportions to fabricate a novel cation exchange membrane based on grafted cellulose acetate with sodium 4-styrenesulfonate (GCA) via solution casting method for direct methanol fuel cell (DMFC) applications. The structure of composite membranes has been examined using FTIR, TGA, SEM, DSC. physicochem...

Two eye fields have been identified in the frontal lobes of primates: one is situated dorsomedially within the frontal cortex and will be referred to as the eye field within the dorsomedial frontal cortex (DMFC); the other resides dorsolaterally within the frontal cortex and is commonly referred to as the frontal eye field (FEF). This review documents the similarities and differences between th...