Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO2/YSZ anode is active for the ...

We investigate the ground state properties of electronic models for doped transition-metal oxides. An effective t J like Hamiltonian is derived from the case of strong Hund coupling between the conduction electrons and localized spins by means of the projection technique. An attractive interaction for conduction electrons and an antiferromagnetic coupling of the localized spin are obtained. A l...

The study of the oxygen incorporation and diffusion in lanthanum manganite thin films is presented by means novel isotope-exchange atom probe tomography, allowing a direct quantification enhancement grain boundaries' kinetics.

We present results of local spin density approximation (LSDA) pseudopotential calculations for the perovskite structure oxide, bismuth manganite (BiMnO3). The origin of the differences between bismuth manganite and other perovskite manganites is determined by first calculating total energies and band structures of the high symmetry cubic phase, then sequentially lowering the magnetic and struct...

This study was conducted to investigate the use of cubic LaMnO3 nano-perovskite as a green catalyst for the degradation of an aqueous solution of methyl orange under different conditions. Nanoscale cubic lanthanum manganite with the particle size of ~20 nm was successfully synthesized via citrate sol-gel method. The sample was characterized using the FT-IR and UV-Vis spectroscopy, XRD, SEM, and...

Mesoporous titanium dioxide co-doped with boron and lanthanum has been prepared by template method using boric acid triethyl ester, lanthanum nitrate hexahydrate and tetrabutyl titanate as precursors and Pluronic P123 as template. The as-prepared photocatalyst is characterized by thermogravimetric differential thermal analysis, N2 adsorption-desorption measurements, X-ray diffraction, scanning ...