This paper reported the fabrication of ternary metallic PtPdBi hollow nanocatalyst through a facile, one-pot, wet-chemical method by adopting sodium borohydride and polyvinylpyrrolidone as reducing agent and surfactant directing agent, respectively. The hollow structure offers novel morphology and large surface areas, which are conducive to enhancing the electrocatalytic activity. The electroca...

The electrocatalytic properties for electro-oxidation reactions of shape-controlled Pt-based catalysts have been improved by alloying with 2nd elements. In this study, we demonstrate cubic PtPd alloy nanoparticles synthesized using a thermal decomposition method. The cubic PtPd nanoparticles exhibit a homogeneous distribution of alloy nanostructures in the presence of Pt and Pd metallic phases....

the combination of graphene (gr) and nickel oxide nanoparticles (nio nps) yields nanostructured electrochemical sensor formed a novel kind of structurally uniform and electrocatalytic activity material. in cyclic voltammetry (cv) studies, in the presence of ep, nio/gr composite modified electrode shows a significantly higher current response for ep oxidation. based on differential pulse voltamm...

Porous Pt nanowire arrays show enhanced electrocatalytic activities for ethanol oxidation in direct alcohol fuel cells.

in this research, we reported a novel modified carbon ceramic electrode (cce) using ni/al layered double hydroxide as modifier was fabricated by sol-gel technique. the ni/al layered double hydroxide modified sol gel derived carbon ceramic (ni/al ldh-sgd-cc) electrode was used for electrocatalytic oxidation of acetaldehyde. the oxidation of acetaldehyde happens at the potential where ni (iii) sp...

For the first time this study reported the success of using nanocrystalline hexagonal close-packed (hcp) nickel (Ni) modified composite graphite (CG) electrode (hcp-nano Ni/CG) for the electrocatalytic oxidation of glycerol in alkaline medium (0.1 M KOH). The hcp-nano Ni/CG electrode had an improve response and specificity on the electrocatalytic oxidation of glycerol over the bare CG. The elec...

For the first time this study reported the success of using nanocrystalline hexagonal close-packed (hcp) nickel (Ni) modified composite graphite (CG) electrode (hcp-nano Ni/CG) for the electrocatalytic oxidation of glycerol in alkaline medium (0.1 M KOH). The hcp-nano Ni/CG electrode had an improve response and specificity on the electrocatalytic oxidation of glycerol over the bare CG. The elec...

We controlled the morphologies of zinc oxide (ZnO) nanostructures on single-walled carbon nanotube electrodes by an electrochemical deposition method and investigated the dependence of the electrocatalytic characteristics toward hydrazine on the different morphologies. ZnO nanorods provided high electrocatalytic activity with unique electrochemical behaviours, associated with the H(+) ion gener...

We report electrocatalytic oxidation of formic acid using monometallic and bimetallic dendrimer-encapsulated nanoparticles (DENs). The results indicate that the Au147@Pt DENs exhibit better electrocatalytic activity and low CO formation. Theoretical calculations attribute the observed activity to the deformation of nanoparticle structure, slow dehydration of formic acid, and weak binding of CO ...