in this paper, the electrochemical behaviour of passive films formed on aisi 321 stainless steel (aisi 321)immersed in 0.1 m naoh + 0.1 m koh solution was evaluated by different electrochemical techniques. forthis purpose, passive films were formed at open circuit potential for 1 to 12 hours and then electrochemicalmeasurements were done. the polarization curves suggested that aisi 321 showed e...

the electrocatalytic degradation of methyl orange (mo) on pbo2-tio2 nanocomposite electrodes was studied by cyclic voltammetry and bulk electrolysis. the results reveal that pbo2-tio2 nanocomposite electrodes possess higher oxygen evolution overpotential than pbo2 electrodes and the electrocatalytic degradation of mo on the electrodes is direct oxidation process. the influence of experimental p...

in this investigation, attempts were directed to study the inhibitive effects of nitrite and phosphate base inhibitors for the carbon steel alloy samples, which are used in an acid gas treatment process (the sulfiran® solution), in fe-edta solution. electrochemical techniques, i.e. polarization curves and electrochemical impedance spectroscopy (eis), were used to evaluate the inhibition efficie...

The main objective of this study is removal of pathogenic bacteria using electrochemical process. The bactericidal effects of electrochemical system containing steel mesh electrode were evaluated from contaminated water with E. coli, Pseudomonas aeroginosa, Staphylococcus aureous and Streptococcus fecalis at various concentrations. Effect of current density, supporting electrolyte and pathogeni...

in the present study, five modeling approaches of ra, mlp, mnn, gff, and canfis were applied so as to estimate the radial overcut values in electrochemical drilling process. for these models, four input variables, namely electrolyte concentration, voltage, initial machining gap, and tool feed rate, were selected. the developed models were evaluated in terms of their prediction capability with m...

This paper presents a model-based approach on the analysis of complex multidisciplinary electrochemical processes, with implementation on a reactor for the electrochemical conversion of CO2 to formate/formic acid. The process is regarded as a system of interacting physical and electrochemical mechanisms. A process model is developed by combining individual mathematical sub-models of the mechani...

background: high concentration of salt makes biological treatment impossible due to bacterial plasmolysis. the present research studies the process of electrochemical oxidation efficiency and optimal levels as important factors affecting ph, salt concentration, reaction time and applied voltage. methods: the sample included graphite electrodes with specifications of 2.5 cm diameter and 15 cm he...

Local electrochemical phenomena on the surfaces of the LaAlO(3)-SrTiO(3) heterostructure are explored using unipolar and bipolar dynamic electrochemical strain microscopy (D-ESM). The D-ESM suggests the presence of at least two distinct electrochemical processes, including fast reversible low-voltage process and slow high-voltage process. The latter process is associated with static surface def...