نتایج جستجو برای: enthalpy of hydrogen dissolution

تعداد نتایج: 21182932  

1996
Jun Yin Bao-Huai Wang Zhi-Fen Li You-Min Zhang Zhen-Nan Gu

Enthalpies of dissolution of C60 and C70 in o-xylene, toluene, and CS2 have been measured by a Calvet MS-80 microcalorimeter at temperatures from 293.15 K to 313.15 K. It was observed that the dissolution of C60 in the three organic solvents in the above range of temperatures was exothermic, while the dissolution of C70 in the same three solvents was endothermic. The enthalpy of dissolution of ...

Journal: :iranian chemical communication 2015
nasrin sohrabi maryam dookheh

in this study at first , an azo dye, 2,7- naphthalenediol, 2-[(4-bromophenyl)azo (bpand) as a ligand has been synthesized by addition of p-bromoaniline to the modified montomorillonite k10 clay. this ligand was characterized using 1h-nmr, uv-vis and ir spectroscopies. subsequently, its interaction with calf thymus deoxyribonucleicacid ,ct-dna was investigated in 5 mm phosphate buffer solution, ...

Thermodynamic study on the interaction of β-CD with poly ethylene oxide and poly acrylic acid was performed by isothermal titration calorimetry at 298K. when β-CD is added to the interpolymer complex, competition is created between host-guest and Hydrogen bond. Enthalpy of interaction between the β-CD and interpolymer complex was calculated using the extended solvation theory. P=1 Shows that w...

Journal: :Reactions 2022

The equilibrium solubility of benzoic acid in water and ethanol, as well nine {ethanol (1) + (2)} mixtures, was determined from T = (293.15 to 323.15) K. Benzoic mole fraction these aqueous-ethanolic mixtures adequately correlated with some well-known correlation/prediction models, obtaining mean percentage deviations 2.2 7.6%. Apparent thermodynamic quantities, namely, Gibbs energy, enthalpy, ...

حسینی, سیدرحمان, شجاع‌رضوی, رضا, قلی‌پور, سلمان,

This study aims at investigation of the hydrogen damage after dissolution annealing and two-stage aging in aluminum 7075 alloy. Dissolution annealing was performed at 500 to 575 °C for duration of 1 to 20 hours. The first stage of two-stage aging was performed at 180, 200 and 220 °C for 30 minutes. The second stage was carried out at 120 and 150 °C for 10, 15 and 20 hours. Structura...

Maryam Dookheh Nasrin Sohrabi,

In this study at first , an azo dye, 2,7- naphthalenediol, 2-[(4-Bromophenyl)azo (BPAND) as a ligand has been synthesized by addition of p-Bromoaniline to the modified montomorillonite K10 clay. This ligand was characterized using 1H-NMR, UV-Vis and IR spectroscopies. Subsequently, its interaction with calf thymus deoxyribonucleicacid ,ct-DNA was investigated in 5 mM phosphate buffer solution, ...

2017
Manuel J Louwerse Ana Maldonado Simon Rousseau Chloe Moreau-Masselon Bernard Roux Gadi Rothenberg

The Hansen solubility parameter approach is revisited by implementing the thermodynamics of dissolution and mixing. Hansen's pragmatic approach has earned its spurs in predicting solvents for polymer solutions, but for molecular solutes improvements are needed. By going into the details of entropy and enthalpy, several corrections are suggested that make the methodology thermodynamically sound ...

2007
Michiel J. van Setten Gilles A. de Wijs Geert Brocks

Mg2NiH4 is a promising hydrogen storage material with fast de hydrogenation kinetics. Its hydrogen desorption enthalpy, however, is too large for practical applications. In this paper we study the effects of transition metal doping by first-principles density functional theory calculations. We show that the hydrogen desorption enthalpy can be reduced by 0.1 eV/H2 if one in eight Ni atoms is rep...

Journal: :Faraday discussions 2011
Steven Tedds Allan Walton Darren P Broom David Book

Porous materials adsorb H2 through physisorption, a process which typically has a rather low enthalpy of adsorption (e.g. ca. 4 to 7 kJ mol(-1) for MOFs), thus requiring cryogenic temperatures for hydrogen storage. In this paper, we consider some of the issues associated with the accurate characterisation of the hydrogen adsorption properties of microporous materials. We present comparative gra...

Journal: :Bioscience reports 1996
N C Singha N Surolia A Surolia

Prediction of thermodynamic parameters of protein-protein and antigen-antibody complex formation from high resolution structural parameters has recently received much attention, since an understanding of the contributions of different fundamental processes like hydrophobic interactions, hydrogen bonding, salt bridge formation, solvent reorganization etc. to the overall thermodynamic parameters ...

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