the interaction of p-sulphonatocalix [6] arene towards l-arginine and l-lysine has been studied inacidic aqueous solution (p1-1 2) using uv-vis spectrophotometric titration technique. the psulphonatocalix[6] arene was found to be able to form 1:1 complexe with amino acids in water.the values of the association constant were determined at different temperatures to evaluate thethermodynamic funct...

the sorption and desorption behaviors of eu(iii) from aqueous solutions with cation exchange resins containing carboxyl groups (d155 resin) were studied in terms of varied eu(iii) concentration, adsorbent dosage, ph, contact time and temperature. batch shaking sorption experiments were carried out to evaluate the performance of d155 resin in the removal of eu(iii) from aqueous solutions. the lo...

The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free e...

2 Thermodynamics 4 2.1 The Foundations of Thermodynamics . . . . . . . . . . . . . . . 4 2.2 Thermodynamic Equilibrium . . . . . . . . . . . . . . . . . . . . 5 2.3 The Conditions for Equilibrium . . . . . . . . . . . . . . . . . . . 7 2.4 The Equations of State . . . . . . . . . . . . . . . . . . . . . . . . 13 2.5 Thermodynamic Processes . . . . . . . . . . . . . . . . . . . . . . 14 2.6 Ther...

Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It is also connected to the Jensen-Shannon divergence, Fisher information, and Rao's entropy differential metric. Therefore, thermodynamic length is of central ...

The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...