Block copolymers offer an interesting platform to study chemically triggered transitions in self-assembled structures. We have previously reported the oxidative degradation of vesicles made of poly(propylene sulfide)-poly(ethylene glycol) (PPS-PEG) copolymers. Here we propose a mechanism for vesicle degradation deduced from copolymer conformational changes occurring at the air/water interface i...

BOITOUT, Hugo, "Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene random copolymer" (2014). Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene random copolymer Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene rando...

Pluronic poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (PEO-PPO-PEO) block copolymers are grafted with poly(vinyl pyrrolidone) by free radical polymerization of vinyl pyrrolidone with simultaneous chain transfer to the Pluronic in dioxane. This modified polymer has both thermal responsiveness and remarkable capacity to interact with a wide variety of hydrophilic and hydrop...

Water vapor sorption in films consisting of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) amphiphilic block copolymers has been measured gravimetrically at air relative humidity in the range 38–94% at 248C. The water sorption isotherm was obtained and compared to data for water vapor desorption (drying) for the same system. The kinetics of water vapor sorption we...

Mesostructured silica-block copolymer thin films are demonstrated to provide orientationally ordered host matrixes for stable alignment of coassembled porphyrin J-aggregates with anisotropic optical properties. Visible light at 490 nm was absorbed anisotropically (A|/A⊥ ) 1.35) by aligned, hexagonally ordered (ethylene oxide)20-(propylene oxide)70-(ethylene oxide)20 (P123) triblock copolymer/si...