نتایج جستجو برای: fe 2
تعداد نتایج: 2581771 فیلتر نتایج به سال:
The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl-methane-thiol in tetra-hydro-furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol-ecule consists of two similar [(μ-2-C(4)H(3)O-CH(2)S)Fe(2)(CO)(6)] moieties joined to a spiro-type four-coordinate μ(4)-S atom such that this bridging sulfur is tetra-hed...
در این پروژه، چهار کمپلکس دو هسته ای با فلزات fe ،co و به صورت کاتیونی- آنیونی با فرمول های ( 1) [fe (bpy)3]2 [co (dipic)2]3 و (2 ( [fe(dipic)2]3 [co(bpy)3] ، [fe(bpy)3][co(ncs)6](3) و (4 )] [fe(dipic)2]3[co(h 2o)6 تهیه شده اند. تمامی این کمپلکس ها توسط تکنیک های ft-ir ، uv- vis ، آنالیز عنصری ، هدایت سنجی و طیف سنجی جذب اتمی aas) ( مورد شناسایی قرار گرفته اند. نتایج این شناسایی ها موید صحیح ...
در این کار تحقیقاتی، شش کمپلکس آهن (iii) لیگاند های باز شیف با دهنده های no2 درون نانو واکنشگاه های mcm-41 و زئولیت کپسولی شدند؛ fe-l1@nax (1)، fe-l2@nax (2)، fe-l3@nax (3)، fe-l4@nax (4)، fe-l3@nax (5)، fe-l1@mcm-41 (6)، ] 2- (1- ( پیریدین- 2- ایل) هیدرازین )کربوکسامید[ (hl1)،] 2- ( 2- هیدروکسی 3- متوکسی بنزیلیدین) هیدرازین کربوکسامید[ (h2l2)، ]2- (2- هیدروکسی 3- متوکسی بنزیلیدین ) هیدرازین کر...
The title compound, [Fe(2)(C(14)H(10)NS(2))(2)(CO)(6)], was synthesized as a structural and biochemical model for the active site of [FeFe]-hydrogenase. The bond lengths (Fe-Fe, Fe-S and Fe-C) and angles (C-Fe-Fe and Fe-S-Fe) are within expected ranges. The S⋯S distance [2.9069 (12) Å] and the dihedral angle between two Fe-S-Fe planes [78.5 (3)°] of the butterfly-shaped Fe(2)S(2) core are enlar...
The purpose of this study was to investigate the relationship between the chemical form and localization of zinc (Zn) in plant leaves and their Zn accumulation capacity. An interspecific cross between Arabidopsis halleri sp. halleri and Arabidopsis lyrata sp. petrea segregating for Zn accumulation was used. Zinc (Zn) speciation and Zn distribution in the leaves of the parent plants and of selec...
When Fe-ions enter into the ZnO NPs, their oxidation state can be tuned and excitonic peak enlarges, indicating that lattice becomes more disordered. The AFM interactions found in paramagnetic NPs become stronger as Fe content increases.
Iron is an essential element for cells but may also be an important cytotoxin. However, very little is known about iron transport, redox status, or toxicity specifically inside cells. In this study, we exploited the sensitivity of fura-2 to quenching by ferrous iron (Fe(2+)) to detect intracellular free iron ([Fe(2+)](i)) in neurons, astrocytes, and oligodendrocytes in primary culture. All cell...
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