A series of first-row-transition-metal ferrite magnetic nanoparticles (NPs) MFe2O4 [M = Mn2+ (1), Fe2+ (2), Co2+ (3), Ni2+ (4), Cu2+ (5) or Zn2+ (6)] were prepared by the co-precipitation method and characterized by Fourier transform infrared (FTIR) spectroscopy, powder X-ray diffraction (XRD), scanning electron microscope energy dispersive X-ray spectrometry (SEM-EDS), vibrating sample magneto...

A series of models for the active site (H-cluster) of the iron-only hydrogenase enzymes (Fe-only H2-ases) were prepared. Treatment of MeCN solutions of Fe2(SR)2(CO)6 with 2 equiv of Et4NCN gave [Fe2(SR)2(CN)2(CO)4](2-) compounds. IR spectra of the dicyanides feature four nu(CO) bands between 1965 and 1870 cm(-1) and two nu(CN) bands at 2077 and 2033 cm(-1). For alkyl derivatives, both diequator...

We present an efficient approach to develop cellulose nanocrystal (CNC) hybrids with magnetically responsive Fe3O4 nanoparticles that were synthesized using the (Fe3+/Fe2+) coprecipitation. After 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-catalyzed oxidation of CNC, carbodiimide (EDC/NHS) was used for coupling amine-containing iron oxide nanoparticles that were achieved by dopamine li...

We present a different strategy for synthesizing the Au-γ-Fe2O3 bifunctional nanoparticle by using a larger (50 nm) Au nanoparticle as the core surrounded by smaller (10 nm) γ-Fe2O3 nanoparticles. The synthesis of the composite nanoparticles is quite facile based on a simple redox process whereby Fe2+ is used to reduce Au3+. The morphology and composition of the product is measured by transmiss...

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Ya Chen Name of the doctoral dissertation Silver nanoparticles embedded in glass by ion exchange method for biosensor applications Publisher School of Electrical Engineering Unit Department of Microand Nanosciences Series Aalto University publication series DOCTORAL DISSERTATIONS 125/2012 Field of research Photonics Manuscript...

In this study, we synthesized water-soluble hyperbranched poly(amido acid)s (HBPAAs) featuring multiple terminal CO2H units and internal tertiary amino and amido moieties and then used them in conjunction with an in situ Fe2+/Fe3+ co-precipitation process to prepare organic/magnetic nanocarriers comprising uniformly small magnetic iron oxide nanoparticles (NP) incorporated within the globular H...

With a large specific surface area, high reactivity, and excellent adsorption properties, nano zerovalent iron (nZVI) can degrade a wide variety of contaminants in wastewater. However, aggregation, oxidation, and separation issues greatly impede its wide application. In this study, MoS₂/Fe₃O₄/nZVI nanocomposites were successfully synthesized by a facile step-by-step approach to overcome these p...

Experiments were performed in parallel using six identical UASB (upflow anaerobic sludge blanket) reactors to examine the effects of iron (Fe2+) on sludge granulation during start-up. Introduction of Fe2+ at concentrations of 300 and 450 mg/L enhanced the granulation process in UASB reactors, while dosage of Fe2+ (150 mg/L) had little effect on the sludge granulation. The Fe2+concentration in g...

in this paper, grafting of acrylic acid monomer on gum tragacanth was performed. variable of experiment included concentration of initiators and monomer, time, and temperature. grafting efficiency was measured in the term of percentage of grafting (%g) and percentage of grafting efficiency (%e). effectiveness of grafted gum in ferrous ion removal at different condition was assessed. according t...