studies of the magnetization of fe2o3@pt nanoparticles at room temperature showed that there is superparamagnetic contribution with high saturation magnetization about 12.35(emu/g), and soft ferromagnetic contribution with narrow coercive field about 58(oe). in this paper we fitted the hystersis loop of sample with brillouin function that demonstrating existence of superparamagnetic phase. tota...

We report here a systematic synthesis and characterization of aligned R-Fe2O3 (hematite), -Fe2O3, and Fe3O4 (magnetite) nanorods, nanobelts, and nanowires on alumina substrates using a pulsed laser deposition (PLD) method. The presence of spherical gold catalyst particles at the tips of the nanostructures indicates selective growth via the vapor-liquid-solid (VLS) mechanism. Through a series of...

a simple and facile method for the preparation offe2+ supported on hydroxyapatite-core-shell-γ-fe2o3 nanoparticles (γ-fe2o3@hap-fe2+ nps) as an environmentally friendly and recyclable green catalyst is described and used for the one-pot synthesis of benzimidazoles and benzoxazole derivatives via reactions between aromatic aldehydes and ortho‐phenylenediamine or ortho‐aminophenol in aqueous medi...

in this study, iron oxide nanoparticles (maghemite) were used to remove ni (ii) and cr (vi) from mine’s waste water. first, by using novel single step, maghemite nanoparticles (?-fe2o3) produced at room temperature, without the use of natural solvents and oxides. the average particle size of the maghemite was estimated to be 14 nm, by transition electron microscope (tem(. various factors influe...

Studies of the magnetization of Fe2O3@Pt nanoparticles at room temperature showed that there is superparamagnetic contribution with high saturation magnetization about 12.35(emu/g), and soft ferromagnetic contribution with narrow coercive field about 58(Oe). In this paper we fitted the hystersis loop of sample with Brillouin function that demonstrating existence of superparamagnetic phase. Tota...

Hollow or porous hematite (α-Fe2O3) nanoarchitectures have emerged as promising crystals in the advanced materials research. In this contribution, hierarchical mesoporous α-Fe2O3 nanoarchitectures with a pod-like shape were synthesized via a room-temperature coprecipitation of FeCl3 and NaOH solutions, followed by a mild hydrothermal treatment (120°C to 210°C, 12.0 h). A formation mechanism bas...

Nano crystals of γ-Fe2O3 (maghemite) were synthesized by emulsion precipitation method using kerosene as oil phase, SPAN80 (sorbitane monooleate) as the surfactant and sodium hydroxide as the precipitating agent. The characterization of the samples by FTIR (Fourier transform infra-red) and XRD (X-ray diffraction) techniques confirmed the formation of γ-Fe2O3 (maghemite). Analysis by SEM (scanni...

The native point defects in Fe2O3 are theoretically investigated using ab initio methods based on the GGA + U formalism. We consider vacancies and interstitials of Fe and O atoms as well as the electron polaron as Fe(II) defects at the host Fe(III) site. The formation energies and charge transition levels are computed for each defect type with careful elimination of size effects of the supercel...

A facile and economic route has been presented for mass production of micro/nanostructured hematite microcrystals based on the wet chemical controllable method. The as-prepared samples were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and UV-Vis absorption spectroscopy. The results showed that the product was mesoporous α -Fe2O3 and near...