a mathematical model for commercial naphtha catalytic reformer of tehran refinery was developed. this model includes three sequencing fixed beds of pt/al2o3 catalyst at the steady state condition using detailed kinetic scheme involving 26 pseudo-components connected by a network of 47 reactions, in the range of c6 to c9 hydrocarbons. the reaction network consisted dehydrogenation, hydrogenation...

.................................................................................................................................................... 1 I – INTRODUCTION .................................................................................................................................... 2 II – BACKGROUND .................................................................................

in this paper, modeling and optimization of fischer-tropsch synthesis is considered in a fixed-bed catalytic reactor using an industrial fe-cu-k catalyst. a one dimensional pseudo-homogenous plug flow model without axial dispersion is developed for converting syngas to heavy hydrocarbons. the effects of temperature, pressure, h2 to co ratio in feed stream, and co molar flow on the mass flow rat...

Compliance with the U.S. drinking water standard for arsenic (As) of 10 microg L(-1) is required in January 2006. This will necessitate implementation of treatment technologies for As removal by thousands of water suppliers. Although a variety of such technologies is available, most require preoxidation of As(III) to As(V) for efficient performance. Previous batch studies with illuminated TiO2 ...

operability analysis as one of the most important bridges between process design and process control helps the process designer to investigate the control issues quite early in the design stage. recently, vinson and georgakis suggested a steady state geometrical operability index as a quantitative measure for assessment of process operability. in this paper, dme fixed-bed reactor is heterogeneo...

a computational fluid dynamic (cfd) study of methanol (meoh) to dimethyl ether (dme) process in an adiabatic fixed-bed reactor is presented. one of the methods of industrial dme production is the catalytic dehydration of meoh. kinetic model was derived based on bercic rate. the parameters of this equation for a specific catalyst were tuned by solving a one-dimensional homogenous model using mat...

In a novel dual bed reactor Fischer-Tropsch synthesis was studied by using two diffrent cobalt catalysts. An alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a Rutenuim promoted cobalt catalyst in the second bed. The activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed r...

Over the past decades, the field of chemical engineering has witnessed an increased interest in unsteady-state processes. Multifunctional, as well as intensified chemical processes, may exhibit instationary behaviour especially when based on periodical operating conditions. Ideally, instationary processes lead to a higher yield and increased selectivities compared to conventional steady-state f...