We describe an unusual galvanic replacement process for facile synthesis of nickel nanostructures by using Cu as a sacrificial template in a deep eutectic solvent (DES) Ethaline. This replacement process occurred through a Galvanic exchange of [NiCl4] ions in Ethaline at 353 K with an immersed Cu substrate, which acted as both reactive template and reductant. The mechanism for this replacement ...

The effect of yoga and relaxation changes in psychophysiological parameters in response to the stress of examination in 75 medical students was studied. Initially five parameters (anxiety level, heart rate, blood pressure, galvanic skin resistance and choice reaction time) were recorded, a month before the examination and on the day of examination. Students were then randomly divided into 3 gro...

Design and fabrication of noble metal nanocrystals have attracted much attention due to their wide applications in catalysis, optical detection and biomedicine. However, it still remains a challenge to scale-up the production in a high-quality, low-cost and eco-friendly way. Here we show that single crystalline silver nanobelts grow abundantly on the surface of biomass-derived monolithic activa...

BACKGROUND The weightlessness caused by prolonged bed rest results in changes in cerebral circulation and thus, brain functions, which is of interest. METHODS We investigated the effects of 45-day, -6° head-down bed rest, which stimulated microgravity, on working memory in 16 healthy male participants. The 2-back task was used to test the working memory variations on the 2nd day before bed re...

The befitting capping capabilities of AsO4(3-) provide a stable Cu2O nanocatalyst from a galvanic reaction between a Cu(II) precursor salt and As(0) nanoparticles. This stable Cu2O hydrosol appears to be a suitable catalyst for the one-electron transfer reversible redox reaction between Eosin Y and NaBH4. The progress of the reaction relates to three different kinetic stages. In the presence of...

Well-defined metallic nanobowls can be prepared by extending the concept of a protecting group to colloidal synthesis. Magnetic nanoparticles are employed as "protecting groups" during the galvanic replacement of silver with gold. The replacement reaction is accompanied by spontantous dissociation of the protecting groups, leaving behind metallic nanobowls.

A simple and versatile approach was developed to generate hierarchical assemblies of ultra-small gold nanocluster thin films using the combination of galvanic reaction and a block copolymer coordinated with gold complex. Variation of the temperature allows effective control over the optical response of these stimuli-responsive organic-nanocluster hybrid structures.

We demonstrate a simple water washing process for large-scale fabrication of highly ordered and aligned rectangular silver nanowire monolayers from polyol systems. These monolayers exhibit unique structure-dependent chemical reactivities for the galvanic replacement reaction with HAuCl(4), and novel gold nanoneedle arrays with sharp tips and a uniform structure have been produced.

Density gradient ultracentrifuge separation has been employed as a process-analysis microsystem combining a microreactor and a separator. As a paradigm, intermediates formed after tens of seconds in the galvanic replacement of Ag nanoplates in high concentrated AuCl(4)(-) solution are captured, providing evidence of the mechanism of the reaction, which is difficult to obtain in other ways.

p-Phosphonic acid calix[4]arenes render high stability to exfoliated graphenes in water. These calix[4]arenes modified graphenes can be used as highly effective substrates to nucleate ultra-small Pd nanoparticles, which in turn serve as galvanic reaction templates for the generation of high density 2D arrays of Pt nanoparticles.