The thermodynamic properties of gases have been understood primarily through phase diagrams of bulk gases. However, observations of gases confined in a nanometer space have posed a challenge to the principles of classical thermodynamics. Here, we investigated interfacial structures comprising either O2 or N2 between water and a hydrophobic solid surface by using advanced atomic force microscopy...

-The occurrence of heterogeneous flow structures in gas-particle flows seriously affects the gas–solid contacting and transport processes in high-velocity fluidized beds. A computational study, using a discrete particle method based on Molecular Dynamics techniques, has been carried out to explore the mechanisms underlying the cluster and the core/annulus structure formation. Based on energy bu...

In this work, molecular dynamics simulation is conducted to explore the shock wave phenomena in a nanodomain in near-field laser–material interaction. A large system consisting of over 800,000 atoms is studied. The work focuses on the kinetic and physical properties of the disturbed gas compression driven by the high speed movement of the molten particulates ejected from the solid target in a n...

background and objectives: analytical methods for volatile organic compounds (vocs) in different samples need extraction of compounds, by applying hazardous solvents. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which proper calibration can allow quantitative determinations of vocs at a very good sensitivity without the use of any organic solvent. vocs...

background: determination of organic pollutants usually requires extraction of the pollutants from samples, using hazard­ous solvent. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which, proper calibra­tion can allow quantitative measurements of organic pollutants at a very good sensitivity without the use of any organic sol­vent. because individual voc...

acetonitrile used as a solvent in manufactures and affects to central nervous system from inhalation exposure. the aim of this study was to develop a micro-solid phase extraction method for  the determination of acetonitrile in the air matrix. the sampling was performed with a small diameter fused silica fiber coated with a thin film of stationary phase and was subsequently desorbed and analyze...

A computational study has been carried out to assess the influence of pressure on the flow behaviors in dense gas-fluidized beds. Therefore the discrete particle simulation approach has been employed to study the regime transitions, local two-phase flow structures and the energy dissipation distribution. The results show that high pressure reduces the incipient fluidization velocity, widens the...