Selective activation of primary C-H bonds for fine chemicals synthesis is of crucial importance for the sustainable exploitation of available feedstocks. Here, we report a viable strategy to synthesize ternary GR-CdS-TiO2 composites with an intimate spatial integration and sheet-like structure, which is afforded by assembling two co-catalysts, graphene and TiO2, into the semiconductor CdS matri...

The semiconductor CdS is generally found in the wurtzite structure. Prior experimental and theoretical results confirm that the semiconductor CdS nanoparticles maintain a wurtzite structure for diameters greater than 6 nm. There is disagreement in the literature for sizes smaller than 6 nm. We use the density-functional theory FIREBALL code and perform finite-temperature molecular dynamics simu...

 Researchers in the field of simulation have been mainly interested in the question of how to increase the efficiency of solar cells. Therefore this study aimed to investigate CdS/CdTe solar cells by applying AMPS-1D software. The impact of semiconductor layers thickness on the output parameters of the CdS/CdTe solar cell is being analyzed and studied carefully, for example, fill factor, effici...

We introduce a facile and robust methodology for the aggregation-free aqueous-phase synthesis of hierarchically complex metal-semiconductor heterostructures. By encapsulating semiconductor nanostructures within a porous SiO(2) shell with a hollow interior, we can isolate each individual particle while allowing it access to metal precursors for subsequent metal growth. We illustrate this by Pt d...

Exposed surfaces of organic-free colloidal semiconductor nanocrystals act as generic luminescent sensors for multiple analytes. S(2-) capped CdSe/CdSeS/CdS core/gradient-shell/shell nanocrystals are turn-on sensors for Cd(2+) ions (110 pM) in an aqueous medium with physiological pH 7.4. A similar organic-free semiconductor nanocrystal shows luminescence turn-off sensing for 2,4,6-trinitrophenol...

Metal chalcogenide semiconductor nanowires are of particular interest for several reasons. First, II-VI semiconductors present a broad range of band gaps (from 0.15 eV in HgTe to 3.68 eV in ZnS). Second, most of them have direct energy gaps making them particularly important for electro-luminescence devices. Third, these kinds of semiconductors can be electrochemically deposited from aqueous so...

the present work deals with the synthesis and characterization of cds nanoparticles with good thermal stability and optical properties by a novel and simple synthetic route. the nanoparticles were synthesized via chemical precipitation method in a single reaction vessel under ambient conditions. the prepared cds nanoparticles were compared with the bulk cds. the optical properties were determin...

CdS nanoparticles are II-VI group semiconductor in nature with suitable band gap for photoluminescence and photo-catalyst applications. CdS nanostructures were synthesized via a facile precipitation method in the presence of green capping agents such as starch, glucose, gelatin, salicylic acid in the green solvent of water. The influence of concentration, surfactant, precipitating agent on the ...

Gallium-doped n-type CdS nanowires (NWs) were successfully synthesized via a thermal evaporation method. The conductivities of the CdS NWs were dramatically improved by nearly nine orders of magnitude after Ga doping, and could be further tuned over a wide range by adjusting the doping level. High-performance metal-insulator-semiconductor field-effect transistors (MISFETs) were constructed base...

The highly organized structure of M13 bacteriophage was used as an evolved biological template for the nucleation and orientation of semiconductor nanowires. To create this organized template, peptides were selected by using a pIII phage display library for their ability to nucleate ZnS or CdS nanocrystals. The successful peptides were expressed as pVIII fusion proteins into the crystalline cap...