ring cleavage occurred when 1,2,4-triazino-1,2,4-triazines (3), (4) and (5) were treated with concentrated hydrochloric acid to yield n-substituted triazines (7) and (8). these confirm the given configuration assigned to the isomeric triazinotriazines. 6-methyl-2-phenyl-7h-oxazolo [3,2-b][1,2,4]-triazin-7-one (9) underwent ring cleavage on treatment with sodium alkoxide to afford 3-alkoxy-1,2,4...

The sequential addition of H⁺ and H⁻ ions to [Mo₂Cp₂(μ-κ²P,S:κ¹P,η⁴-SPMes*)(CNtBu)(CO)₂] (Mes* = 2,4,6-C₆H₂tBu₃) completes a hydrocarbation or hydronitration of the uncoordinated C=C bond of the Mes* ring, yielding new ligands with thiophosphinidene and aldimine or aminocarbene functions tethered to a η⁴-cyclohexadiene ring. The H⁻ ion first attacks a Cp group to give a cyclopentadiene complex ...

The diversification of late stage synthetic intermediates provides significant advantages in efficiency in comparison to conventional linear approaches. Despite these advantages, accessing varying ring scaffolds and functional group patterns from a common intermediate poses considerable challenges using existing methods. The combination of regiodivergent nickel-catalyzed C-C couplings and site-...

Density functional theory calculations have been employed to investigate the mechanism of gold(I)-catalysed rearrangements of cyclopropenes. Product formation is controlled by the initial ring-opening step which results in the formation of a gold-stabilised carbocation/gold carbene intermediate. With 3-phenylcyclopropene-3-methylcarboxylate, the preferred intermediate allows cyclisation via nuc...

Ring cleavage occurred when 1,2,4-triazino-1,2,4-triazines (3), (4) and (5) were treated with concentrated hydrochloric acid to yield N-substituted triazines (7) and (8). These confirm the given configuration assigned to the isomeric triazinotriazines. 6-Methyl-2-phenyl-7H-oxazolo [3,2-b][1,2,4]-triazin-7-one (9) underwent ring cleavage on treatment with sodium alkoxide to afford 3-alkoxy-1...

The reductive ring opening reaction conditions for the simple [60]fullerenyldihydropyrrole 1 have been optimized to include acetic acid in the reaction mixture to rapidly protonate the anionic intermediate. Under these conditions, the ring opened dihydrofullerene 2 was obtained in 68% yield. Under slightly modified conditions and at −78 °C, the reductive bis-ring opening of the tethered trans-4...

In this paper, we investigate the generalized Hyers-Ulam-Rassias and the Isac and Rassias-type stability of the conditional of orthogonally ring $*$-$n$-derivation and orthogonally ring $*$-$n$-homomorphism on $C^*$-algebras. As a consequence of this, we prove the hyperstability of orthogonally ring $*$-$n$-derivation and orthogonally ring $*$-$n$-homomorphism on $C^*$-algebras.

Density functional theoretical calculations are used to elucidate the epoxidation mechanism of styrene with a cytochrome P450 model Compound I, and the formation of side products. The reaction features multistate reactivity (MSR) with different spin states (doublet and quartet) and different electromeric situations having carbon radicals and cations, as well as iron(III) and iron(IV) oxidation ...

Ligands for neuronal receptors are important for understanding the biological functions as well as for treatment of neuronal diseases associated with. Here, we report diverted synthesis and biological evaluation of four C-ring analogs of IKM-159, a subtype-selective inhibitor for (S)-2-amino-3-(3-hydroxy-5-methyl-4-isoxazolyl)propionic acid (AMPA)-type ionotropic glutamate receptor. Starting fr...