نتایج جستجو برای: intermediate ring

تعداد نتایج: 251397  

Journal: :Organic letters 2013
Jun Deng Ruofan Li Yijie Luo Jian Li Shupeng Zhou Yongjian Li Jingyu Hu Ang Li

A divergent approach was developed toward the total synthesis of taiwaniaquinoids. An advanced intermediate 5a with trans A/B ring junction was concisely assembled by employing a Bi(OTf)3-catalyzed cationic cyclization and a Wolff-type ring contraction as key steps. This common intermediate was readily converted to racemic taiwaniaquinones A and F and taiwaniaquinols B and D, respectively.

2012
Dongting Liu Hua Ji Xiuhui Lu

The mechanism of the cycloaddition reaction between singlet state dichlorosilylene germylidene (Cl2Si=Ge:) and acetone has been investigated with B3LYP/6-31G* and B3LYP/6-31G** method, from the potential energy profile, we predict that the reaction has one dominant reaction pathway. The presented rule of the reaction is that the two reactants firstly form a Si-heterocyclic four-membered ring ge...

Journal: :Indian journal of biochemistry & biophysics 2001
D Bhattacharyya G K Das D P Burma

The mechanism of protein synthesis is still unknown due to inability to detect the so-called enzyme "peptidyl transferase" even after elucidation of high-resolution crystal structure of ribosome. We have recently shown by model building and semi-empirical energy calculation that the tRNA molecule at P-site of ribosome may act as peptidyl transferase (Das et al. (1999) J. Theor. Biol. 200, 193-2...

Journal: :علوم 0

in this note we introduce the notion of weak mccoy rings as a generalization of mccoy rings, and investigate their properties. also we show that, if is a semi-commutative ring, then is weak mccoy if and only if is weak mccoy.

Journal: :iranian journal of catalysis 2016
zinat gordi mohammad vazan

substituted 2, 4- diphenyl quinolines were synthesized by a multicomponent domino reaction of anilines, aldehydes and terminal aryl alkynes. the synthetic pathway involves the formation of an imine, followed by the intermolecular addition of an alkyne to the imine. this intermediate immediately undergoes ring closure and oxidative aromatization. the reaction is catalyzed by natural kaolin, a st...

Abdollah Javidan Ali Salmani Mohammad Javad Taghizadeh

HIE-124 is a new member of ultra-short acting hypnotics’ drug family. In this research, the synthesis ofanalogues of HIE-124 drug in the heterocyclic thiazole ring replaced to thiadiazole, will be presented.Thiadiazolodiazepines during a two-step reaction starting from the amino thiadiazole resultedfrom-various derivatives of benzoic acid and thiosemicarbazide were synthesized. In the first ste...

Journal: :International Journal of Solids and Structures 2006

Journal: :The Journal of organic chemistry 2012
Pedro J Silva

Substituted pyrroles may be synthesized from selected 1,2-pyridazines through a reductive ring contraction involving the addition of four electrons and four protons. Our density functional theory computations of this reaction mechanism show that the first reduction event must be preceded by the uptake of one proton by 1,2-pyridazine and that the reaction proceeds through a 2e(-)/3H(+)-bearing i...

A. Javidan A. Salmani M. J. Taghizadeh

HIE-124 is the new member of ultra-short acting hypnotics drug family. In this research, thiadiazole can act as the bio-isosteric replacement of thiazole in synthesized compounds as HIE-124 derivatives. HIE-124 drug, in which the heterocyclic thiazole ring replaced to thiadiazole, will be presented. Thiadiazolodiazepines were synthesized by a two-step reaction starting from the amino thiadiazol...

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