This research group is studying structure and dynamics of molecules and clusters by two-color double resonance spectroscopy. New spectroscopic methods will also be developed to observe the higher vibrational state under collision-free condition. A molecular cluster is a microscopic system of solution and/or crystal, and is thought to provide detailed information on relaxation and reaction dynam...

In this work, we investigate the vibrational properties of the hybrid organic/inorganic halide perovskite MAPbI3 (MA = CH3NH3) in the range 6−3500 cm−1 by combining first-principles density-functional perturbation theory calculations and low-temperature infrared (IR) absorption measurements on evaporated perovskite films. By using a group factor analysis, we establish the symmetry of the normal...

Diagnosis of periodontal disease by Fourier transform infrared (FT-IR) microscopic technique was achieved for saliva samples. Twenty-two saliva samples, collected from 10 patients with periodontal disease and 12 normal volunteers, were pre-processed and analyzed by FT-IR microscopy. We found that the periodontal samples showed a larger raw IR spectrum than the control samples. In addition, the ...

A new microspectroscopic technique was applied to the analysis of occluding deposits in xylem elements of Quercus serrata. The production of this substance is believed to be a defense response of the sapwood against fungal infection. An occluding substance about 10 μm across was analyzed by Infrared-Scanning Near-field Optical Microscopy (IR-SNOM), which allows for the measurement of IR spectru...

Although, that the solar energy is important for life continuity, there is need to protect large buildings from these radiations in summer and if the buildings are permitted to take these radiations, the cost of cooling will be too much. One of the most effective methods used to solve this problem is to coat buildings with specific pigments that reflect the solar infrared radiation. This wo...

Current digital camera sensors are inherently sensitive to the near-infrared part of the spectrum. To prevent the near-IR contamination of images, an IR blocking filter (hot mirror) is placed in front of the sensor. In this work, we start by replacing the camera’s hot mirror by a piece of clear glass, thus making the camera sensitive to both visible and near-IR light. Using a pair of lens-mount...

Infrared detectors can be used for a variety of applications such as: using in fiber-optic communications. Conventional technology for IR detectors is using p-i-n structure based on GaAs compound. This paper reports on the design and modeling of an IR detector using a p-i-n GaAs structure. Comsol software is used to simulate the model and the detector is discussed for terminal current, dopant p...

A new selection procedure of an informative near-infrared (NIR) region for regression model building is proposed that uses an online NIR/mid-infrared (mid-IR) dual-region spectrometer in conjunction with two-dimensional (2D) NIR/mid-IR heterospectral correlation spectroscopy. In this procedure, both NIR and mid-IR spectra of a liquid sample are acquired sequentially during a reaction process u...

The infrared (IR) spectrum of protonated azulene (AzuH(+), C(10)H(9)(+)) has been measured in the fingerprint range (600-1800 cm(-1)) by means of IR multiple photon dissociation (IRMPD) spectroscopy in a Fourier transform ion cyclotron resonance mass spectrometer equipped with an electrospray ionization source using a free electron laser. The potential energy surface of AzuH(+) has been charact...