In isotactic poly(methyl methacrylate) (PMMA), we investigate the dynamics of the ester methyl groups by means of deuteron magnetic resonance (DMR) in a deuterated sample. We find that the motion of the CD(3)-group affects the deuteron spin-lattice relaxation as well as the DMR line shape in a characteristic way. Quadrupolar order spin lattice relaxation measurements between T=291 K and T=70 K ...

The UNIQUAC activity coefficient model is extended to predict solid-liquid equilibrium of isotactic crystalline poly (1-butene), iPBu-1, in different organic solvents. The UNIQUAC activity coefficient model used in this work is based on the concept of group contribution and consists of combinatorial, residual and free volume terms. To account for branching of atom groups in the monomer structur...

We report the preparation and single-molecule observation of a high molecular weight C60-end-capped, stereoregular poly(methyl methacrylate) (PMMA-C60) with a precisely controlled structure. The highly isotactic PMMA-C60 (mm = 98%) with a narrow molecular weight distribution was synthesized by the stereospecific anionic living polymerization of tert-butyl methacrylate followed by end-capping wi...

High-pressure in situ x-ray diffraction and specific-volume measurements on isotactic poly(4-methyl-1-pentene) melt have uncovered abrupt changes in the pressure dependence of microscopic structure as well as that of macroscopic density. The first sharp diffraction peak of the polymer melt, which is related to the intermediate-range order and is explained as resulting from the correlations betw...

When a minor semicrystalline phase is dispersed in an immiscible blend with another polymer the form of isolated droplets, its crystallization behavior dominated by nucleation. In particular, nucleation can occur bulk volume (homogeneous nucleation), at surface possible nucleating foreign impurities, or interface matrix polymer. Dispersed poly(butene-1) (PB) and polycaprolactone (PCL) droplet p...

Conformational characteristics and configurational properties of poly(1-methylphosphirane) (PMePP) and poly(1-phenylphosphirane) (PPhPP) have been predictively elucidated by the refined rotational isomeric state scheme coupled with ab initio molecular orbital and density functional calculations. The lone pair of the phosphorus atom adopts an sp hybrid orbital. Owing to the high s character (50%...