The hydrolysis of sodium borohydride as a source of hydrogen gas is studied at different mole ratios of H+ to NaBH4. The sulfonated porous carbon (SPC) is used as a source of hydrogen ion and catalyst. It is found that the sulfonated porous carbon exhibits high activity for the hydrolysis of NaBH4 to generate hydrogen gas at room temperature in comparison to Amberlyst-15 and Nafion-NR50. The ki...

in this research oxidation kinetic panceuo.s (p.s) by s2o8-2 at the presence of agno3 ascatalyst was studied.the method was spectrophotometer following absorption spectrum (p.s) inwave length of 518 nm. after improving the condition such as ph, p.s concentration, k2s2o8concentration, ionic strength, temperature, rate constant, activation energy, constant frequency,order reaction and thermo dyna...

reaction constants and heat release during thermophilic aerobic digestion of typical secondary and mixed sludges were determined. maximum reaction constant, determined by measuring the amounts of biodegradable volatile suspended solids (bvss) removed, occurred in the temperature range of 55-60 ºc. measurement of heat releases were carried out, at the same range, by the aid of a temperature prog...

Reaction constants and heat release during thermophilic aerobic digestion of typical secondary and mixed sludges were determined. Maximum reaction constant, determined by measuring the amounts of biodegradable volatile suspended solids (bVSS) removed, occurred in the temperature range of 55-60 ºC. Measurement of heat releases were carried out, at the same range, by the aid of a temperature ...

The pseudo-first order rate constants and activation parameters have been determined using two methods, constant-temperature kinetic (CTK) and variable temperature kinetic (VTK), for the oxidative addition reactions of [Pt2Me2(C^N)2(µ-dppf)], (1a, C^N = deprotonated 2-phenylpyridine (ppy); 1b, C^N = deprotonated benzo[h]quinoline (bhq)) with MeI. The results obtained from VTK method are in agre...

a study of the biokinetics of anaerobic digestion of municipal solid waste (msw) was carried out using anaerobic batch digester. from the experimental results, the kinetic parameters (coefficient values) of the digestion of the msw were determined. the maximum rate of substrate utilization (k), saturation constant (ks), endogenous decay coefficient (kd), biomass yield or microbial growth yield ...

In this research oxidation kinetic panceuo.s (P.S) by S2O8-2 at the presence of AgNO3 ascatalyst was studied.The method was spectrophotometer following absorption spectrum (P.S) inwave length of 518 nm. After improving the condition such as PH, P.S concentration, K2S2O8concentration, ionic strength, temperature, rate constant, activation energy, constant frequency,order reaction and thermo dyna...

in the present study, advanced oxidation treatment, uv/ was applied to decolourisation of acid orange 8 (ao8). the uv radiation was carried out with a 15 w low-pressure mercury lamp. kinetic model for the decolourisation of the dye was developed based on experimental results and known chemical and photochemical reactions. the observed kinetic reaction constant was determined and correlated as a...